Seamless Steel Pipe for Steam Injection Yield Strength

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Solution Overview

Problem

Current steel pipes for steam injection in the asphalt extraction process from oil sand lack sufficient high-temperature strength, with yield stresses at 350°C being lower than the required 555 MPa, limiting the use of higher temperature and pressure steam for more efficient asphalt extraction.

Innovation Solution

A seamless steel pipe with a specific chemical composition (C: 0.03-0.08%, Si: 0.05-0.5%, Mn: 1.5-3.0%, Mo: 0.4-1.2%, Al: 0.005-0.100%, Ca: 0.001-0.005%, N: 0.002-0.015%, P: ≤0.03%, S: ≤0.01%, Cu: ≤1.5%, and optional Cr, Nb, Ti, Ni, V) that is water-cooled after hot working, quenched, and tempered to achieve a yield stress of at least 600 MPa at 350°C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional steel compositions and annealing processes are used, then manufacturing simplicity is maintained, but yield strength at 350°C remains below 555 MPa

Engineering Contradiction:
Improveyield strength at 350°CVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by optimizing the chemical composition parameters (C: 0.03-0.08%, Si: 0.05-0.5%, Mn: 1.5-3.0%, Mo: 0.4-1.2%, etc.) and heat treatment parameters (water cooling rate, quenching temperature, tempering temperature) to achieve yield strength ≥600 MPa at 350°C, resolving the contradiction between strength improvement and manufacturing complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of martensite and retained austenite through controlled cooling and heat treatment processes. This composite microstructure provides both high strength (martensite) and ductility (retained austenite), achieving yield strength ≥600 MPa at 350°C while maintaining manufacturability

Inventive Principle:
Principle #40Composite materials

2Productivity

If higher temperature and pressure steam is used, then asphalt extraction efficiency is improved, but the risk of hydrogen-induced cracking and weldability deterioration increases

Engineering Contradiction:
Improveasphalt extraction efficiencyVSAvoidresistance to hydrogen-induced cracking
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters, particularly controlling C content (0.03-0.08%) to avoid excessive carbide formation that would reduce toughness, while optimizing Mn (1.5-3.0%) and Mo (0.4-1.2%) contents to enhance high-temperature strength and resistance to hydrogen-induced cracking, enabling safer use of higher temperature steam

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent prioritizes bulk material properties (chemical composition and microstructure) over complex protective measures, using a cost-effective composition formulation that inherently provides resistance to hydrogen-induced cracking and maintains weldability, avoiding the need for expensive additional protective systems

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The steel pipe achieves enhanced high-temperature strength and toughness, allowing for the use of higher temperature and pressure steam while maintaining weldability and reducing the risk of hydrogen-induced cracking.

Implementation Method 1

water cooling the seamless steel pipe after rolling from a temperature of not lower than the A 3 point to a temperature of 450°C or lower

Methodology Applied
Scientific EffectWater cooling: Cooling

Implementation Method 2

quenching the water cooled seamless steel pipe from a temperature of higher than the Ac 3 point and at most 1000°C

Methodology Applied
Scientific EffectQuenching: Heat Treatment

Implementation Method 3

tempering the quenched seamless steel pipe at a temperature of at most the Ac 1 point

Methodology Applied
Scientific EffectTempering: Heat Treatment

Data Source

PatentEP2548987B1Seamless steel pipe for steam injection, and method of manufacturing same
Publication Date: 2018.08.15 NIPPON STEEL & SUMITOMO METAL CORP
  • EP2548987B1 patent drawingFigure 1
  • EP2548987B1 patent drawingFigure 2
  • EP2548987B1 patent drawingFigure 3~4

AI summary

There is provided a steel pipe for steam injection having high yield stress even at 350°C. The seamless steel pipe for steam injection according to the present invention has a chemical composition comprising, by mass percent, C: 0.03 to 0.08%, Si: 0.05 to 0.5%, Mn: 1.5 to 3.0%, Mo: more than 0.4 to 1.2%, Al: 0.005 to 0.100%, Ca: 0.001 to 0.005%, N: 0.002 to 0.015%, P: at most 0.03%, S: at most 0.01%, and Cu: at most 1.5%, the balance being Fe and impurities. The seamless steel pipe is manufactured by being water cooled after hot working and by being quenched and tempered.