Surface Sizing Agent for Security Paper Adhesion

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Solution Overview

Problem

Existing surface sizing agents for security papers fail to provide long-lasting adhesion of security elements, resistance to dirt and mechanical stress, and maintain print stability under extreme conditions, while also being incompatible with security features and requiring primer application.

Innovation Solution

A surface sizing agent comprising a binder with polyvinyl alcohol and polyurethane components, a carbodiimide crosslinking agent, and a dispersant primarily consisting of water, which allows for direct gluing of security elements without primer and enhances the paper's resistance to dirt and mechanical stress.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional surface sizing agents are applied to security paper, then the paper surface strength and hydrophobicity are improved, but the adhesion of security elements deteriorates over time

Engineering Contradiction:
Improvesurface strengthVSAvoidadhesion durability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the sizing agent by incorporating specific polymers (polyvinyl alcohol, carboxymethylcellulose, starch) and controlled amounts of inorganic fillers (alumina, silica). This compositional parameter change enables the sizing agent to simultaneously provide surface strength and long-term adhesion for security elements without degradation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite sizing agent formulation combining organic polymers (PVA, CMC, starch) with inorganic components (alumina, silica) and optional adhesion promoters. This composite structure provides both the surface properties needed for printability and the chemical stability required for durable security element bonding over time.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If surface sizing is applied to enhance print stability, then print quality is improved, but the paper becomes more susceptible to soiling

Engineering Contradiction:
Improveprint stabilityVSAvoidsoiling susceptibility
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The sizing agent creates a localized modified surface layer with specific properties: the polymer matrix provides print stability and surface strength, while the inorganic fillers (alumina, silica) provide soiling resistance. This local quality differentiation allows the surface to simultaneously resist soiling and maintain print stability without compromising either property.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If security elements are bonded after storage of sized substrate material, then production flexibility is improved, but adhesion strength deteriorates

Engineering Contradiction:
Improveproduction flexibilityVSAvoidbonding strength
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The sizing agent is applied to the security paper substrate in advance during paper production, creating a stable surface layer that maintains its adhesion properties during storage. This preliminary action ensures that when security elements are bonded later (after storage periods of weeks or months), the adhesion strength remains high without requiring re-sizing or primer application.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention eliminates the need for expensive and time-consuming primer applications before bonding security elements. The sizing agent itself provides long-term adhesion capability, replacing the traditional multi-step process (sizing + storage + primer + bonding) with a simplified process (sizing + storage + direct bonding), thereby improving production flexibility and reducing costs.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Stability of the object's composition

If polyvinyl alcohol is used as the primary binder, then surface hydrophobicity is improved, but adhesion to security elements deteriorates

Engineering Contradiction:
ImprovehydrophobicityVSAvoidadhesion strength
Core Design Contradiction:
Stability of the object's compositionVSStrength

Solution Approach 1:

The patent creates a composite binder system where polyvinyl alcohol provides the base hydrophobicity and surface properties, while carboxymethylcellulose and starch contribute additional adhesion mechanisms. The inorganic fillers (alumina, silica) further enhance adhesion through mechanical interlocking and chemical interactions, creating a multi-functional composite that simultaneously achieves hydrophobicity and strong adhesion.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The surface sizing agent ensures long-lasting adhesion of security elements and prints, improves resistance to dirt and mechanical stress, and maintains print stability under extreme conditions, allowing for storage and printing without pre-treatment, while being compatible with security features and cost-effective.

Implementation Method 1

a crosslinking agent for the polyvinyl alcohol and/or the polyurethane, wherein the crosslinking agent is a carbodiimide

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

The surface sizing partially penetrates the paper and also forms a film on the paper surface

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

increases the paper's hydrophobicity to limit its absorbency

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentEP4357521A1Surface sizing agent for a security paper, method for surface sizing a security paper substrate material, security paper and value document
Publication Date: 2024.04.24 GIESECKE & DEVRIENT CURRENCY TECHNOLOGY GMBH
  • EP4357521A1 patent drawing
  • EP4357521A1 patent drawing

AI summary

The invention relates to a surface sizing agent for security paper, comprising a binder, a crosslinking agent, and a dispersion agent, wherein the binder has a polyvinyl alcohol component and a polyurethane component, the crosslinking agent is a carbodiimide, and the dispersion agent consists of at least 95% water by mass. The invention also relates to a method for surface sizing a security paper substrate material with the surface sizing agent, a method for further processing the security paper substrate material into security paper, as well as a security paper substrate material, a security paper, and a security document, each of which has surface sizing with the surface sizing agent according to the invention.