Segmented Hueing Agent Particles in Laundry Detergent

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Solution Overview

Problem

Laundry detergent powders face challenges in achieving even distribution of hueing agents on fabric surfaces while minimizing undesirable spotting, which affects their whiteness and dingy cleaning performance.

Innovation Solution

A solid free-flowing particulate laundry detergent composition is developed, comprising a specific combination of hueing agent particles and spray-dried particles, including alkyl benzene sulphonate anionic detersive surfactant, silicate salt, sodium carbonate, and carboxylate polymer, optimized in terms of weight percentages and particle architecture to enhance distribution and reduce spotting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hueing agents are incorporated into laundry detergent powder to improve whiteness and cleaning performance, then cleaning effectiveness is improved, but uneven distribution on fabric surface and spotting negatives occur

Engineering Contradiction:
Improvecleaning effectivenessVSAvoiddistribution uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The hueing agent is segmented into separate particles distinct from the surfactant particles. This segmentation allows the hueing agent to be distributed independently and evenly across the fabric surface without clumping with surfactants, thereby achieving uniform distribution while maintaining effective cleaning performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention applies local quality by creating separate particle types with specific functions: hueing agent particles for whiteness enhancement and surfactant particles for cleaning. This functional separation ensures that each component performs its specific role effectively, with the hueing agent providing localized whiteness improvement without interfering with overall cleaning uniformity.

Inventive Principle:
Principle #3Local quality

2Illumination intensity

If hueing agents are incorporated into laundry detergent powder to enhance whiteness performance, then fabric whiteness is improved, but undesirable spotting negatives occur

Engineering Contradiction:
Improvefabric whitenessVSAvoidspotting negatives
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

By segmenting the hueing agent into separate particles rather than incorporating it into surfactant particles, the invention prevents localized concentration of hueing agent that would cause spotting. The separate particle structure ensures even dispersion throughout the detergent formulation, improving whiteness while eliminating spotting negatives.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The separate particle structure acts as an intermediary mechanism that prevents direct interaction between hueing agent and surfactant that would cause spotting. This physical separation serves as a mediator that allows both components to function independently and effectively, with the hueing agent enhancing whiteness without creating harmful spotting effects.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved whiteness and dingy cleaning performance with more even hueing agent distribution and minimized spotting, leading to better fabric cleaning results.

Implementation Method 1

from 8 wt % to 24 wt % alkyl benzene sulphonate anionic detersive surfactant

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS9957470B2Solid free-flowing particulate laundry detergent composition
Publication Date: 2018.05.01 PROCTER & GAMBLE CO
  • US9957470B2 patent drawing
  • US9957470B2 patent drawing
  • US9957470B2 patent drawing

AI summary

A solid free-flowing particulate laundry detergent composition comprising: (a) from 0.1 wt % to 5 wt % hueing agent particle comprising: (i) from 2 wt % to 10 wt % hueing agent, wherein the hueing agent has the following structure:wherein:R1 and R2 are independently selected from H; alkyl; alkoxy; alkyleneoxy; alkyl capped alkyleneoxy; urea; and amido;R3 is a substituted aryl group;X is a substituted group comprising sulfonamide moiety; and(ii) from 60 wt % to 98 wt % clay; and (b) from 35 wt % to 80 wt % spray-dried particle comprising: (a) from 8 wt % to 24 wt % alkyl benzene sulphonate anionic detersive surfactant; (b) from 5w % to 18 wt % silicate salt; (c) from 0 wt % to 10 wt % sodium carbonate; and (d) from 0 wt % to 5 wt % carboxylate polymer.