Segregated Steam System for Hydrogen Production

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Solution Overview

Problem

In hydrogen production facilities, the steam produced from process condensate can contain residual organic compounds, making it unsuitable for export and requiring segregated steam systems to prevent contamination, which are not easily retrofittable into existing heat exchange networks and lack high thermal efficiency.

Innovation Solution

A segregated steam system and process that uses two separate steam drums to segregate boiler feed water from process condensate and make-up water, with indirect heat exchange to heat and cool the boiler feed water, allowing for the separation of steam for internal use and export, while maintaining high thermal efficiency and ease of retrofitting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a segregated steam system is used to prevent organic compound contamination in export steam, then steam quality for export is improved, but system complexity and retrofitting difficulty increase

Engineering Contradiction:
Improvesteam qualityVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The steam system is divided into two separate steam drums: a first steam drum for process condensate and a second steam drum for make-up water. This segmentation physically separates the contamination sources, allowing export steam to be generated only from the second drum while the first drum handles process condensate steam for internal use only, thereby ensuring steam quality without requiring complete system redesign

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The harmful organic compounds are extracted from the steam generation process by preventing process condensate from entering the export steam pathway. The first steam drum containing process condensate is isolated and its steam is routed only to internal process use, effectively extracting the contamination risk from the export steam system

Inventive Principle:
Principle #2Taking out (Extraction)

2Manufacturing precision

If a segregated steam system is used to prevent organic compound contamination in export steam, then steam quality for export is improved, but retrofitting ease deteriorates

Engineering Contradiction:
Improvesteam qualityVSAvoidretrofitting ease
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The system uses two separate steam drums that can be independently configured and integrated into existing facilities. The first steam drum handles process condensate while the second handles make-up water, allowing retrofits to be implemented by adding or modifying specific drum components rather than redesigning the entire steam system

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Both steam drums can serve multiple functions: the second steam drum provides export steam while also potentially supplying steam to the process, and the first steam drum handles process condensate recovery. This multi-functionality allows the segregated system to adapt to various existing facility configurations, improving retrofitting ease

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Use of energy by moving object

If process condensate is used in steam generation, then thermal efficiency is improved, but steam quality deteriorates due to organic compound contamination

Engineering Contradiction:
Improvethermal efficiencyVSAvoidsteam quality
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The system segments steam generation into two separate pathways: one for process condensate (first steam drum) and one for make-up water (second steam drum). This allows process condensate to be thermally processed and its heat recovered without contaminating export steam, maintaining thermal efficiency while ensuring steam quality for export applications

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different quality requirements are applied to different steam uses: process steam can tolerate organic compounds and is generated from process condensate in the first drum, while export steam requires high purity and is generated only from make-up water in the second drum. This local quality differentiation maintains thermal efficiency by utilizing process condensate where appropriate while ensuring steam quality where required

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively produces steam suitable for both internal use and export, preventing organic compound contamination and achieving high thermal efficiency with minimal equipment cost increase, allowing for easy integration into existing hydrogen production facilities.

Implementation Method 1

reacting the reformer feed gas mixture in a reforming reaction under reaction conditions effective to form a reformate

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

indirect heat exchange to heat and cool the boiler feed water

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

producing steam in a segregated steam system

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP3771688B1Segregated steam system and process in a hydrogen production facility
Publication Date: 2021.10.27 AIR PROD & CHEM INC
  • EP3771688B1 patent drawingFigure 1

AI summary

A segregated steam system and process in a hydrogen production facility wherein boiler feed water is heated by indirect heat exchange with a reformate, the heated boiler feed water is used to heat water condensate formed from the reformate, the heated water condensate is passed to a first steam drum for producing steam for a reformer feed gas mixture, and a second portion of the heated boiler feed water is passed to a second steam drum for producing steam for export.