Area-Selective AR Coatings for Multi-Band Silicon Detectors

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Solution Overview

Problem

Silicon-based detectors face challenges in achieving high quantum efficiency across the entire UV to NIR wavelength range due to silicon's varying optical properties, requiring different coatings for different portions of the detector to optimize detector response.

Innovation Solution

The implementation of area-selective atomic layer deposition (ALD) of antireflection (AR) and bandpass filter coatings on silicon-based light detectors, using lithography-based patterning to deposit coatings with different materials and thicknesses on specific portions, creating a butcher-block style response profile that targets specific bandpasses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a single uniform coating is applied across the entire detector surface, then the manufacturing process is simple, but the quantum efficiency cannot be optimized across different wavelength ranges due to silicon's varying optical properties

Engineering Contradiction:
Improvecoating application simplicityVSAvoidquantum efficiency across wavelength range
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies different AR coating materials and thicknesses to different regions of the detector surface. Specifically, the detector is divided into multiple zones (e.g., first region with first AR coating, second region with second AR coating), where each region has optimized coating properties tailored to its intended wavelength range. This local differentiation enables high quantum efficiency across the entire UV to NIR spectrum while maintaining a unified detector structure.

Inventive Principle:
Principle #3Local quality

2Reliability

If different coatings with different materials and thicknesses are applied to different portions of the detector, then the quantum efficiency is optimized for specific bandpasses, but the manufacturing process complexity increases

Engineering Contradiction:
Improvequantum efficiency optimizationVSAvoidcoating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The detector surface is segmented into distinct regions, each receiving a specific AR coating configuration. The patent describes dividing the detector into multiple portions (first portion, second portion, etc.), where each portion is assigned a particular coating material and thickness optimized for its target wavelength band. This segmentation strategy enables precise spectral optimization without requiring a completely complex manufacturing process, as each segment can be processed independently using standard deposition techniques.

Inventive Principle:
Principle #1Segmentation

3Reliability

If area-selective ALD with lithography-based patterning is used to deposit coatings, then the detector response is optimized for specific bandpasses, but the manufacturing time and process steps increase

Engineering Contradiction:
Improvebandpass optimizationVSAvoidmanufacturing cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

Lithography-based patterning is performed before the ALD deposition process to pre-def the regions where different coatings will be applied. By establishing the spatial pattern in advance, the subsequent area-selective ALD process can efficiently deposit materials only in the intended regions without requiring complex in-situ patterning or multiple deposition cycles. This preliminary action streamlines the overall manufacturing sequence.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes area-selective ALD, which enables precise control over coating deposition by varying process parameters such as precursor exposure, temperature, and pressure across different spatial zones. This parameter control allows the same ALD equipment to deposit different materials or thicknesses in different regions through programmed parameter changes, reducing the need for multiple separate deposition tools or processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances quantum efficiency to greater than 50% for UV wavelengths between 110 nm and 300 nm, improving detector performance and reducing optical design complexity while maintaining high throughput and sensitivity across the UV spectral range.

Implementation Method 1

selectively depositing one or more antireflection (AR) and/or bandpass filter coatings on the detector, wherein the AR and/or bandpass filter coatings are selectively deposited on different portions of the light detector

Methodology Applied
Scientific EffectAtomic layer deposition: Chemical Vapour Deposition

Data Source

PatentUS20240038803A1Process for area-selective atomic layer deposition of antireflection coatings and filters
Publication Date: 2024.02.01 CALIFORNIA INST OF TECH
  • US20240038803A1 patent drawing
  • US20240038803A1 patent drawing
  • US20240038803A1 patent drawing

AI summary

A process for fabricating a light detector with one or more antireflection (AR) and/or bandpass filter coatings deposited thereon by area-selective atomic layer deposition (ALD). The AR coatings may comprise a metal oxide or a metal fluoride, such as AlF3, Al2O3, and/or HfO2, and the bandpass filter coatings may comprise solar-blind bandpass filter coatings. The AR and/or bandpass filter coatings may be deposited with different thicknesses on different portions of the light detector using an intentional and controllable patterning by a lithography-based process. As a result, the AR and/or bandpass filter coatings provide a butcher-block style response profile with each of the different portions of the light detector targeting a specific bandpass of light. The AR and/or bandpass filter coatings comprise a linear variable filter (LVF) that provides a spatially varying response by the light detector.