Selective Electroless Deposition on 3D Printed Structures

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Solution Overview

Problem

Current 3D printing methods are limited in creating functional devices with complex, three-dimensional structures due to the need for multiple printing techniques and extensive optimization, which results in excessive build time and limited applicability, as they often require non-functional structural materials and struggle with depositing various materials at pre-defined locations within the structure.

Innovation Solution

A method of electroless selective material deposition that forms multi-material 3D structures with differentially charged regions, allowing for the selective deposition of metals and other materials based on surface charges, using a process that includes forming a 3D structure with negatively, positively, and neutral charged polymers, exposing it to a deposition catalyst, and allowing autocatalysis for material attachment in charged regions, while avoiding neutral regions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If multiple printing techniques are used to create functional devices with complex 3D structures, then manufacturing precision and functionality are improved, but build time and process complexity increase excessively

Engineering Contradiction:
Improveprecision of material depositionVSAvoidbuild time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The structure is segmented into differentially charged regions (positive, negative, neutral) that can be selectively targeted. This allows different materials to be deposited in specific regions through charge-based selection, enabling complex functional structures to be created in a single printing process rather than requiring multiple sequential printing techniques.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the surface charge parameter of different regions within the 3D structure. By creating regions with different charge states (positive, negative, neutral), the system enables selective material deposition based on charge attraction/repulsion, thereby achieving high manufacturing precision without requiring multiple printing passes or techniques.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If multiple printing techniques are employed to deposit various materials at pre-defined locations, then material placement precision is improved, but device complexity and optimization requirements increase

Engineering Contradiction:
Improvematerial placement precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Surface charge acts as an intermediary mechanism that mediates between the printed structure and the materials to be deposited. By assigning different charge states to different regions, the system creates a selective attraction field that guides material deposition to predetermined locations without requiring complex multi-technique processes or extensive optimization.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If non-functional structural materials are used in 3D printing, then structural integrity is maintained, but functionality and material efficiency are reduced

Engineering Contradiction:
Improvestructural integrityVSAvoidfunctional applicability
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The invention applies local quality by creating regions with different charge properties (positive, negative, neutral) within the structural material. This allows the same base material to serve dual purposes: maintaining structural integrity while enabling selective deposition of functional materials in specific regions, thereby eliminating the need for separate non-structural functional materials.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the creation of complex 3D structures with functional materials by selectively depositing metals and other materials at specific locations, reducing the need for multiple printing techniques and optimizing material usage, thereby enhancing the efficiency and functionality of 3D printed devices.

Implementation Method 1

a positively charged deposition catalyst associates or attaches to negatively charged region(s), wherein a negatively charged deposition catalyst attaches to positively charged region(s)

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

forming a multi-material three-dimensional (3D) structure with at least two polymers selected from the group consisting of: a negatively charged polymer, a positively charged polymer, and a neutral polymer

Methodology Applied
Scientific EffectIonic charging: Ionisation

Data Source

PatentUS11999097B2Selective deposition of materials for composite structures via additive manufacturing
Publication Date: 2024.06.04 VIRGINIA TECH INTELLECTUAL PROPERTIES INC
  • US11999097B2 patent drawing
  • US11999097B2 patent drawing
  • US11999097B2 patent drawing

AI summary

Described herein are electroless material deposition methods and techniques that can be used to deposit one or more materials on a structure in a selective manner such that deposition can occur in predetermined areas. The methods and techniques of selective electroless material deposition methods described herein can be used to selectively deposit material(s) on 3D printed structures. In some aspects, the 3D structures can contain micro-features that can have one or more materials selectively deposited on their surface in one or more locations.