Selective Gas Trapping via Membrane Segmentation

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Solution Overview

Problem

Existing devices for trapping flammable gases like hydrogen in containment enclosures with radioactive materials face challenges due to gas poisoning by compounds like carbon monoxide, which reduces their effectiveness, and require continuous operation to prevent accumulation, especially in environments with unpredictable hydrogen production.

Innovation Solution

A containment enclosure with a selective filter that allows flammable gases to pass while blocking poisonous gases, using a combination of a microporous layer and a metal membrane to create a partial pressure gradient for hydrogen trapping, and allowing easy replacement of active means when saturated.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If active means are placed directly in the containment enclosure to trap flammable gases, then hydrogen trapping efficiency is improved, but the active means are poisoned by carbon monoxide and other poisonous gases reducing effectiveness

Engineering Contradiction:
Improvehydrogen trapping efficiencyVSAvoidactive means effectiveness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The system is segmented into two distinct zones: a first zone containing the active means for hydrogen trapping, and a second zone containing the gas mixture source. This spatial segmentation prevents direct contact between the active means and poisonous gases while maintaining hydrogen transfer capability through the separating membrane.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A selective membrane acts as an intermediary between the gas mixture and the active means. This membrane selectively permits hydrogen passage while blocking carbon monoxide and other poisonous gases, thereby protecting the active means from poisoning while maintaining hydrogen trapping functionality.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If filters are used to block poisonous gases, then active means are protected from poisoning, but large quantities of active product are necessary due to difficulty in optimizing distribution

Engineering Contradiction:
Improveprotection from poisoningVSAvoidquantity of active product
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

A selective membrane with specific porosity and molecular sieve properties is employed. This porous material inherently blocks poisonous gases like carbon monoxide while permitting hydrogen passage, eliminating the need for large quantities of active product and optimizing the distribution of trapping capacity throughout the system.

Inventive Principle:
Principle #31Porous materials

3Productivity

If oxidation recombiners are used to trap hydrogen, then hydrogen recombination into water is achieved, but sufficient oxygen must be present in the gas overhead which is not always true

Engineering Contradiction:
Improvehydrogen recombination efficiencyVSAvoidoperational conditions flexibility
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The system changes the operational parameter from requiring oxygen presence to operating under varying oxygen conditions. By using a membrane-based selective trapping mechanism instead of oxidation recombination, the system adapts to environments with unpredictable oxygen availability while maintaining hydrogen trapping effectiveness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively traps hydrogen while preventing poisoning gases from interfering with the active means, ensuring continuous operation and efficient gas capture even in environments with variable hydrogen production.

Implementation Method 1

a selective filter that allows flammable gases to pass while blocking poisonous gases

Methodology Applied
Scientific EffectMolecular sieve filtration: Molecular Sieve

Implementation Method 2

using a combination of a microporous layer and a metal membrane to create a partial pressure gradient for hydrogen trapping

Methodology Applied
Scientific EffectPartial pressure gradient: Pressure Gradient

Implementation Method 3

create a partial pressure gradient for hydrogen trapping

Methodology Applied
Scientific EffectSelective permeation: Permeation

Data Source

PatentEP2673782B1Device for trapping flammable gases produced by radiolysis or thermolysis in a containment
Publication Date: 2015.03.11 TN INT (FR)
  • EP2673782B1 patent drawingFigure 1~3
  • EP2673782B1 patent drawingFigure 4~5
  • EP2673782B1 patent drawingFigure 6

AI summary

A device for trapping flammable gases such as hydrogen comprises active means (3) inside a casing (1) which is closed except for openings which are plugged by filters (2) that normally allow only the gases that are to be trapped to pass through them. The trapping maintains a reduced pressure inside the casing, which continually draws in the gases produced outside. The trap can operate without any maintenance and for long periods of time, even in a completely enclosed environment.