Selective Graphene Growth on Semiconductor Surfaces for Low Resistance

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Solution Overview

Problem

Existing semiconductor devices face challenges in preventing resistance increase due to reduced metal wiring widths and require effective barrier materials, with conventional methods struggling to accurately form graphene layers on desired regions and being prone to residue and oxide formation.

Innovation Solution

A semiconductor device is developed with a graphene layer grown directly on a semiconductor substrate using a plasma-enhanced chemical vapor deposition (PECVD) process, selectively forming the graphene layer only on the semiconductor surface, avoiding the insulator and allowing for precise control over growth time to achieve desired thickness and region specificity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional methods are used to form graphene layers, then graphene can be formed on substrate surfaces, but the graphene layers cannot be accurately formed on desired regions and residue and oxide formation occur

Engineering Contradiction:
Improveregion specificity of graphene layer formationVSAvoidresidue and oxide formation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by making the substrate surface have different properties in different regions. The insulator regions and semiconductor regions are treated differently during the graphene formation process, allowing graphene to selectively grow only on desired semiconductor regions while preventing growth on insulator regions. This resolves the contradiction by enabling precise regional control without residue formation.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies preliminary action by performing surface treatment or patterning of the substrate before the graphene formation process. By pre-defining the regions where graphene should form (through insulator placement or surface modification), the subsequent graphene deposition occurs only in predetermined areas, achieving high manufacturing precision and preventing harmful residue formation.

Inventive Principle:
Principle #10Preliminary action

2Area of moving object

If metal wiring width is reduced to increase integration density, then device miniaturization is achieved, but resistance increases

Engineering Contradiction:
Improvemetal wiring widthVSAvoidresistance
Core Design Contradiction:
Area of moving objectVSReliability

Solution Approach 1:

The patent applies composite materials by combining graphene with existing semiconductor structures. Graphene, with its superior electrical conductivity, is integrated into the metal wiring system to create a composite conductive path. This allows the wiring to maintain low resistance even when the overall width is reduced, as the graphene component compensates for the increased resistance that would normally result from smaller cross-sections.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by introducing a new material (graphene) with different electrical properties into the wiring system. Graphene's high electron mobility and conductivity fundamentally change the electrical parameters of the wiring structure, enabling reduced dimensions without the associated resistance penalty that would occur with conventional metals alone.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of a semiconductor device with a graphene layer that effectively addresses resistance issues by selectively growing graphene on the semiconductor surface, improving precision and reducing residue and oxide formation, thus enhancing device performance.

Implementation Method 1

a graphene layer grown directly on a semiconductor substrate using a plasma-enhanced chemical vapor deposition (PECVD) process

Methodology Applied
Scientific EffectPlasma-enhanced chemical vapor deposition: Plasma Enhanced Chemical Vapour Deposition

Data Source

PatentUS12027589B2Semiconductor device including graphene and method of manufacturing the semiconductor device
Publication Date: 2024.07.02 SAMSUNG ELECTRONICS CO LTD
  • US12027589B2 patent drawing
  • US12027589B2 patent drawing
  • US12027589B2 patent drawing

AI summary

Provided is a semiconductor device including graphene. The semiconductor device includes: a substrate including an insulator and a semiconductor; and a graphene layer configured to directly grow only on a surface of the semiconductor, wherein the semiconductor includes at least one of a group IV material and a group III-V compound.