Selenium Recovery from Wastewater Using Pseudomonas stutzeri

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Solution Overview

Problem

Current methods for wastewater treatment, such as coagulation precipitation and chelate treatment, are costly and inefficient for recovering selenium from wastewater due to low selenium content in chemical sludge, and existing biological treatments face challenges in optimizing conditions for effective selenium recovery.

Innovation Solution

A method using Pseudomonas stutzeri NT-I microorganisms to reduce water-soluble selenium compounds into elemental or gaseous selenium, involving specific temperature, pH, and aeration conditions in a jar fermenter system, allowing for efficient recovery of selenium from wastewater.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If coagulation precipitation or chelate treatment is used to clean wastewater, then wastewater can be treated, but treatment cost increases and selenium cannot be recovered as a resource

Engineering Contradiction:
Improvewastewater treatment effectivenessVSAvoidtreatment cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent converts the harmful toxic selenium compounds in wastewater into beneficial elemental selenium through biological reduction. The microorganism Pseudomonas stutzeri NT-I reduces selenate and selenite into elemental selenium, which is non-toxic and can be recovered as a resource, thus transforming a waste treatment problem into a resource recovery opportunity

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent replaces conventional chemical treatment methods (coagulation precipitation, chelate treatment) with a biological treatment system using microorganisms. This substitution eliminates the need for chemical reagents and sludge disposal, reducing treatment costs while enabling selenium recovery

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional chemical treatment methods are used, then wastewater can be cleaned, but selenium content in chemical sludge is low and selenium cannot be recovered

Engineering Contradiction:
Improvewastewater cleaning capabilityVSAvoidselenium recovery
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The microorganism transforms dissolved selenium compounds into solid elemental selenium through biological reduction, concentrating selenium into a recoverable form rather than dispersing it in chemical sludge. This enables selenium recovery as a resource while maintaining wastewater cleaning effectiveness

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent utilizes phase transition from dissolved selenium compounds (selenate/selenite in aqueous phase) to solid elemental selenium (precipitated phase) through biological reduction. This phase change concentrates selenium into a form that can be easily separated and recovered from the treated wastewater

Inventive Principle:
Principle #36Phase transitions

3Loss of substance

If biological treatment method using Pseudomonas stutzeri NT-I is used, then selenium can be recovered, but treatment conditions must be optimized for efficient recovery

Engineering Contradiction:
Improveselenium recovery efficiencyVSAvoidtreatment condition optimization
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The patent optimizes treatment parameters including pH (maintained at alkaline conditions), temperature, and aeration to maximize selenium recovery efficiency. By controlling these parameters, the system achieves efficient conversion of selenate and selenite into elemental selenium while simplifying the overall treatment process

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the efficient recovery of selenium by converting toxic water-soluble selenium compounds into non-toxic, water-insoluble elemental or gaseous forms, facilitating recycling and reducing treatment costs.

Implementation Method 1

Pseudomonas stutzeri NT-I is capable of efficiently reducing selenate into selenite and further reducing selenite into elemental selenium

Methodology Applied
Scientific EffectBiological reduction: Reduction

Implementation Method 2

converting toxic water-soluble selenium compounds into non-toxic, water-insoluble elemental or gaseous forms

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS10047378B2Method for recovering selenium
Publication Date: 2018.08.14 SHIBAURA INST OF TECH
  • US10047378B2 patent drawing
  • US10047378B2 patent drawing
  • US10047378B2 patent drawing

AI summary

An object of the present invention is to provide a method for efficiently recovering solid selenium or gaseous selenium from wastewater/waste using a microorganism. The present invention provides a method for recovering selenium, comprising reducing a water-soluble selenium compound so as to produce elemental selenium or gaseous selenium by allowing a sample containing a water-soluble selenium compound to come into contact at a temperature which is more than 35° C. and is 40° C. or less at pH 7.0 to 9.4 with a microorganism capable of producing elemental selenium or gaseous selenium through reduction of a water-soluble selenium compound.