Self-Aligned Quantum Dot Structure for Precise Spacing Control

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Solution Overview

Problem

Existing quantum dot manufacturing methods face challenges in achieving precise placement and tunability of quantum dots, particularly in inter-dot spacing, and struggle with making electrical contacts at high precision, especially at elevated temperatures, limiting their application in quantum computing devices.

Innovation Solution

A method involving the formation of conductive ridges, insulative layers, and semiconductor-alloyed spacer islands, followed by thermal oxidation to create symmetrical quantum dots with self-aligned electrodes, allowing for size and spacing control compatible with CMOS manufacturing processes, enabling high-temperature operation and precise alignment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If quantum dots are formed by chemical synthesis with good size tunability, then size control is improved, but placement precision deteriorates

Engineering Contradiction:
Improvesize controlVSAvoidplacement precision
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The patent introduces spacer islands as intermediary structures that mediate between the quantum dot formation process and the final placement configuration. These spacers act as self-aligned templates that define precise inter-dot spacing while allowing size tunability through controlled material deposition and etching processes

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The method performs preliminary formation of spacer islands and conductive ridges before quantum dot placement. The spacer islands are pre-formed with controlled dimensions and positions, establishing a template that guides subsequent quantum dot formation and ensures precise placement without requiring post-formation adjustment

Inventive Principle:
Principle #10Preliminary action

2Measurement precision

If quantum dots are formed by epitaxial growth with placement precision, then placement control is improved, but size tunability deteriorates

Engineering Contradiction:
Improveplacement precisionVSAvoidsize tunability
Core Design Contradiction:
Measurement precisionVSManufacturing precision

Solution Approach 1:

The patent employs parameter changes in the semiconductor-alloyed layer composition (varying alloy ratios) and deposition conditions to control quantum dot size while maintaining placement precision. By adjusting material parameters such as alloy composition and layer thickness, the quantum dot dimensions can be tuned independently of their spatial positions

Inventive Principle:
Principle #35Parameter changes

3Length of moving object

If lithography is used to form quantum dots with small sizes, then size reduction is improved, but uniformity and reproducibility deteriorate

Engineering Contradiction:
Improvequantum dot sizeVSAvoiduniformity and reproducibility
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

The quantum dots are formed through self-organized processes where the spacer islands and conductive ridges automatically define the quantum dot positions and dimensions. This self-service mechanism eliminates the need for high-resolution lithographic patterning, achieving uniform and reproducible quantum dot formation through self-aligned material segregation and phase separation

Inventive Principle:
Principle #25Self-service

4Length of stationary object

If nanoscale closely-coupled quantum dots are formed, then inter-dot spacing is improved, but electrode fabrication complexity deteriorates

Engineering Contradiction:
Improveinter-dot spacingVSAvoidelectrode fabrication complexity
Core Design Contradiction:
Length of stationary objectVSDevice complexity

Solution Approach 1:

The patent transitions from planar electrode fabrication to three-dimensional self-aligned electrode structures. Conductive ledges are formed vertically on the spacer islands, enabling electrodes to reach closely-coupled quantum dots in the vertical dimension rather than requiring complex lateral routing at the nanoscale

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

5Length of moving object

If quantum dot size is reduced to 5 nanometers or less, then quantum confinement is improved, but manufacturing difficulty deteriorates

Engineering Contradiction:
Improvequantum dot sizeVSAvoidmanufacturing difficulty
Core Design Contradiction:
Length of moving objectVSEase of manufacture

Solution Approach 1:

The patent replaces mechanical lithographic patterning with materials science-based self-organization mechanisms. Quantum dots of 5 nanometers or less are formed through controlled material segregation, phase separation, and self-assembly processes during thermal oxidation and annealing, rather than through mechanical removal or deposition at the resolution limit of lithography

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of quantum dots with sizes down to 5 nanometers or less, achieving high controllability and reproducibility, suitable for large-scale quantum computing, and allows quantum transport at temperatures above 100 K, including room temperature, with improved electrode alignment and quantum performance.

Implementation Method 1

forming symmetrical quantum dots and their cladding-layers of silicon dioxide through thermal oxidation of the semiconductor-alloyed (such as SiGe-alloyed) spacer islands

Methodology Applied
Scientific EffectThermal oxidation: Oxidation

Implementation Method 2

the Si content is preferentially oxidized forming cladding silicon dioxide and the Ge content is segregated and then ripened for forming Ge quantum dots

Methodology Applied
Scientific EffectSegregation:

Implementation Method 3

the Ge content is segregated and then ripened for forming Ge quantum dots

Methodology Applied
Scientific EffectOstwald ripening: Ostwald Ripening

Data Source

PatentUS12107155B2Self-organized quantum dot semiconductor structure
Publication Date: 2024.10.01 NAT YANG MING CHIAO TUNG UNIV
  • US12107155B2 patent drawing
  • US12107155B2 patent drawing
  • US12107155B2 patent drawing

AI summary

The invention provides a self-organized quantum dot semiconductor structure. The quantum dot semiconductor structure includes: a conductive ridge on a substrate; an insulative layer covering the substrate and the conductive ridge, wherein the insulative layer includes a top portion and two sidewalls over the conductive ridge; a semiconductor mechanism of etching back and thermal oxidation, implemented on a semiconductor-alloyed layer set on the insulative layer; a plurality of quantum dots respectively embedded within a plurality of silicon dioxide spacer islands based on the semiconductor mechanism, the quantum dots and the silicon dioxide spacer islands adhered to the sidewalls of the insulative layer; and a plurality of conductive ledges adhered to the silicon dioxide spacer islands, wherein each of the conductive ledges is a portion of an electrode self-alignment to the quantum dot.