Self-Aligning Liquid Crystal Media Without Polyimide Layers

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Solution Overview

Problem

Conventional liquid-crystal display (LCD) technologies, particularly VA and VA-IPS displays, face challenges in achieving homeotropic alignment without polyimide layers, which are costly and can interact with the liquid crystal medium, affecting electrical resistance and limiting suitable components.

Innovation Solution

The use of self-alignment additives with bifunctional or polyfunctional anchor groups that induce homeotropic alignment in liquid-crystalline media, eliminating the need for polyimide layers and allowing for polymerization to stabilize alignment and act as a passivation layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polyimide alignment layers are used to achieve homeotropic alignment, then alignment is achieved, but production costs increase and interactions with liquid crystal medium occur affecting electrical resistance

Engineering Contradiction:
Improvealignment stabilityVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the polyimide alignment layer from the display structure by using self-aligning liquid crystal compounds that can induce homeotropic alignment on their own through specific molecular structures with rigid cores and flexible chains, thereby simplifying the overall device structure and reducing production complexity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The liquid crystal compounds are designed with self-aligning capabilities through specific molecular structures (rigid core with flexible chains) that automatically induce homeotropic alignment on substrate surfaces without requiring external alignment layers, making the system self-sufficient and eliminating dependency on polyimide layers

Inventive Principle:
Principle #25Self-service

2Reliability

If polyimide alignment layers are used, then homeotropic alignment is achieved, but costs increase and suitable liquid crystal components are limited

Engineering Contradiction:
Improvealignment qualityVSAvoidcomponent selection flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The liquid crystal compounds possess inherent self-aligning properties through their molecular structure (rigid core with flexible chains), enabling them to automatically achieve homeotropic alignment without polyimide layers, thus expanding component selection flexibility while maintaining alignment quality

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention changes the molecular structure parameters of liquid crystal compounds by incorporating rigid cores (cyclic or chain structures) with flexible chains, which fundamentally alters their surface interaction properties to enable self-alignment and expands the range of suitable liquid crystal materials

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional alignment methods are used, then alignment is achieved, but response times are slow

Engineering Contradiction:
Improvealignment stabilityVSAvoidresponse time
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The self-aligning liquid crystal compounds rapidly achieve homeotropic alignment through their intrinsic molecular structure properties, eliminating the slow alignment process associated with polyimide layers and significantly improving response times while maintaining alignment stability

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The liquid crystal compounds are pre-designed with specific molecular structures (rigid core with flexible chains) that are prepared in advance to automatically induce homeotropic alignment upon contact with substrates, eliminating the need for time-consuming alignment layer processing and accelerating the overall response time

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the production process, reduces costs, and enhances display performance by achieving homeotropic alignment at lower additive concentrations, improving response times, contrast, and temperature stability while maintaining the advantages of VA technology.

Implementation Method 1

self-alignment additives with an at least one bifunctional or polyfunctional anchor group, which effects the homeotropic (vertical) alignment of the LC media at a surface

Methodology Applied
Scientific EffectHomeotropic alignment:

Implementation Method 2

The LC media may be supplemented by a polymerizable or polymerized component, which serves for stabilisation of the alignment, for adjustment of the tilt angle and/or as passivation layer

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 3

The principle of electrically controlled birefringence, the ECB effect or also DAP (deformation of aligned phases) effect

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 4

liquid-crystalline phases must have high values for the ratio of the elastic constants K 3 /K 1 , high values for the optical anisotropy Δn and values for the dielectric anisotropy of Δε ≤ -0.5

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Data Source

PatentEP2931838B1Liquid-crystal displays and liquid-crystalline media having homeotropic alignment
Publication Date: 2017.08.16 MERCK PATENT GMBH
  • EP2931838B1 patent drawing
  • EP2931838B1 patent drawing
  • EP2931838B1 patent drawing

AI summary

The present invention relates to liquid-crystalline media (LC media) having negative or positive dielectric anisotropy comprising self-alignment additives (SAMs) with an at least one bifunctional or polyfunctional anchor group, which effects the homeotropic (vertical) alignment of the LC media at a surface or the cell walls of a liquid-crystal display (LC display). The invention therefore also encompasses LC displays having homeotropic alignment of the liquid-crystalline medium (LC medium) without conventional imide alignment layers. The LC media may be supplemented by a polymerizable or polymerized component, which serves for stabilisation of the alignment, for adjustment of the tilt angle and/or as passivation layer.