Self-Cleaning Coating With Covalently Bonded Digestive Enzymes

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Solution Overview

Problem

Surfaces such as automobile coatings and paints face challenges in preventing and reducing stain accumulation from bird droppings, bug wastes, food debris, and other materials, as existing technologies are ineffective in enzymatically decomposing stain molecules without using corrosive or oxidative components.

Innovation Solution

Incorporation of digestive proteins like lysozymes, proteases, lipases, and cellulases onto surfaces, utilizing covalent bonding to create a self-cleaning composition that enzymatically decomposes stain molecules, ensuring ongoing stain reduction and elimination without environmental harm.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If regular automatic brush-free washing is used, then cleaning is convenient, but it cannot effectively remove hard-to-remove stains such as insect-originated stains

Engineering Contradiction:
Improvecleaning convenienceVSAvoidstain removal effectiveness
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies preliminary action by incorporating digestive enzymes into the coating before stain formation occurs. The enzymes are pre-positioned on the surface to immediately begin decomposing stain molecules as soon as they contact the coating, preventing stain set-in before regular washing can be performed.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The coating performs self-service by containing digestive enzymes that automatically decompose stains without requiring external intervention. The enzymes continuously break down stain molecules (proteins, polysaccharides, fats) as they contact the surface, enabling the coating to clean itself without manual washing.

Inventive Principle:
Principle #25Self-service

2Reliability

If corrosive or oxidative components are used for stain removal, then stain elimination is effective, but environmental harm is caused

Engineering Contradiction:
Improvestain elimination effectivenessVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces chemical-mechanical systems (corrosive/oxidative cleaners) with a biological system. Digestive enzymes naturally occurring in the environment are used to decompose stains through biochemical catalysis, substituting harsh chemical mechanisms with environmentally benign enzymatic reactions that break down stain molecules into harmless substances.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent converts the harmful property of stains (adhesive proteins, polysaccharides, fats) into beneficial decomposition products. The digestive enzymes transform these potentially harmful stain components into harmless breakdown products, effectively converting the harmful staining action into a beneficial cleaning process that protects the environment.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Productivity

If enzymes are physically adsorbed onto the surface, then initial stain decomposition activity is present, but enzyme longevity is limited

Engineering Contradiction:
Improveinitial enzyme activityVSAvoidenzyme longevity
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent creates a composite material system where digestive enzymes are covalently bonded to the coating matrix. This composite structure integrates the enzyme with the coating through chemical bonds, forming a stable hybrid material that maintains enzyme activity while preventing enzyme leaching or denaturation, thereby extending operational longevity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies preliminary action by covalently bonding enzymes to the coating during the manufacturing process, before the coating is applied or used. This pre-establishment of strong chemical bonds ensures that enzymes remain firmly attached and active throughout the service life of the coating, preventing premature enzyme loss.

Inventive Principle:
Principle #10Preliminary action

4Productivity

If enzymes are incorporated into the coating, then ongoing self-cleaning is enabled, but manufacturing complexity increases

Engineering Contradiction:
Improveself-cleaning capabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges the enzyme incorporation step with the existing coating manufacturing process. By integrating enzyme covalent bonding into the conventional coating formulation and application steps, the patent combines two functions (coating application and enzyme immobilization) into a unified manufacturing process, minimizing additional complexity while enabling self-cleaning functionality.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The self-cleaning composition effectively reduces and eliminates stains through enzymatic degradation, providing long-lasting protection and stability, with covalent bonding enhancing enzyme longevity and activity, even under varying environmental conditions.

Implementation Method 1

The catalytic activity of the digestive proteins enables ongoing self-cleaning to reduce and eliminate stain contaminations. The mechanism of action of these digestive proteins is mainly enzymatic in nature

Methodology Applied
Scientific EffectEnzymatic degradation: Enzyme

Implementation Method 2

digestive proteins including lysozymes, proteases, lipases, cellulases, etc., onto surfaces such as paints and coatings

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

Incorporation of digestive proteins like lysozymes, proteases, lipases, and cellulases onto surfaces, utilizing covalent bonding to create a self-cleaning composition

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Data Source

PatentUS12139701B2Biofunctional materials
Publication Date: 2024.11.12 TOYOTA MOTOR CO LTD
  • US12139701B2 patent drawing
  • US12139701B2 patent drawing
  • US12139701B2 patent drawing

AI summary

Provided are methods and compositions for self-cleaning that include a digestive protein capable of decomposing stain forming molecules, a substrate applied to a solid surface, and a linker moiety bound to an outer surface of said substrate and an active group of said digestive protein, said linker moiety between said protein and said substrate and covalently linking said protein to a surface of said substrate by an amide bond, the linker moiety between a free amine of said protein and said outer surface of said substrate wherein the digestive protein forms a layer on a surface of said substrate such that the digestive protein is surface exposed for reaction with a stain.