Self-Cleaning Surface Layer with Photocatalytic Nanopores

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Solution Overview

Problem

Existing surfaces such as touch screens, glasses, and camera lenses often retain oils and organic residues, which interfere with their functionality and aesthetics, necessitating a self-cleaning solution.

Innovation Solution

A multifunctional self-cleaning surface layer comprising an inorganic matrix with photocatalytic active particles and nanopores, capable of decomposing organic residues with water and electromagnetic radiation, is developed. The layer includes silicon and oxygen, with photocatalytic active particles like titanium dioxide and boron-doped fluorinated diamond-like carbon, and features nanopores that enhance reactivity by storing water molecules.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional surfaces are used, then manufacturing is simple, but organic residues accumulate and interfere with functionality

Engineering Contradiction:
Improvesurface layer formationVSAvoidorganic residue accumulation
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The surface layer incorporates a porous structure with controlled pore sizes (0.5-5 nm) that allows water molecules to penetrate and access organic residues. The porosity enables capillary action to draw water into the layer where photocatalytic reactions occur, directly addressing the residue accumulation problem while maintaining manufacturability through sol-gel processing

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention creates a composite material system combining inorganic matrix (silica, titania), organic components (surfactants, polymers), and photocatalytic particles. This composite structure integrates multiple functions: the inorganic matrix provides structural stability, organic components control surface energy and porosity, and photocatalytic particles enable decomposition of residues, resolving the contradiction between simple manufacturing and effective residue removal

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If photocatalytic particles are added to decompose residues, then self-cleaning capability improves, but device complexity increases

Engineering Contradiction:
Improveorganic residue decompositionVSAvoidsurface layer composition
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The invention merges multiple functional components into a single integrated surface layer applied in one coating process. Photocatalytic particles (titania, zinc oxide), inorganic matrix formers (silica precursors), porosity agents, and surface energy modifiers are combined in a slurry that is applied and fired in a single step, reducing manufacturing complexity despite the multifunctional nature of the final layer

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention controls the size parameter of photocatalytic particles (0.1-10 micrometers) and pore sizes (0.5-5 nm) to optimize performance while maintaining manufacturability. By controlling particle size distribution and pore dimensions through formulation parameters rather than complex processing steps, the system achieves effective residue decomposition without proportionally increasing device complexity

Inventive Principle:
Principle #35Parameter changes

3Productivity

If nanopores are created to store water, then photocatalytic reactivity increases, but manufacturing precision requirements increase

Engineering Contradiction:
Improvephotocatalytic reaction rateVSAvoidpore size control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention uses porosity-generating agents (surfactants, polymers, inorganic fillers) that create controlled pore structures during the firing process. These agents decompose or reorganize at specific temperatures to form pores of predetermined sizes (0.5-5 nm), enabling water storage and enhanced photocatalytic activity without requiring ultra-precise manufacturing control

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention controls pore size through formulation parameters (surfactant concentration, particle size distribution, slurry composition) rather than through complex manufacturing processes. By adjusting these parameters, pore sizes of 0.5-5 nm are achieved, which is sufficient for water molecule access and photocatalytic efficiency without demanding extreme manufacturing precision

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The surface layer effectively decomposes and removes organic residues, maintaining the cleanliness and readability of surfaces, while also having anti-reflective properties and potential antimicrobial effects.

Implementation Method 1

In the presence of water and electromagnetic radiation, the plurality of photocatalytic active particles may facilitate a decomposition reaction of any oil or organic residue on the multifunctional self-cleaning surface layer

Methodology Applied
Scientific EffectPhotocatalysis: Photo-oxidation

Implementation Method 2

Water molecules may be disposed within at least a portion of the plurality of nanopores

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 3

a plurality of nanopores defined within the inorganic matrix in regions corresponding to the bonds between the plurality of photocatalytic active particles and the inorganic matrix

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11772086B2Multifunctional self-cleaning surface layer and methods of forming the same
Publication Date: 2023.10.03 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US11772086B2 patent drawing
  • US11772086B2 patent drawing
  • US11772086B2 patent drawing

AI summary

A multifunctional self-cleaning surface layer and methods of preparing the multifunctional self-cleaning surface layer are provided. The multifunctional self-cleaning surface layer includes an inorganic matrix including silicon and oxygen; a plurality of photocatalytic active particles distributed within and bonded to the inorganic matrix; and a plurality of nanopores defined within the inorganic matrix in regions corresponding to bonds between the plurality of photocatalytic active particles and the inorganic matrix. Water molecules may be disposed within at least a portion of the plurality of nanopores. In the presence of water and electromagnetic radiation, the plurality of photocatalytic active particles may facilitate a decomposition reaction of any oil or organic residue on the multifunctional self-cleaning surface layer.