Self-Emulsifying Polypropylene Resin Adhesion

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Solution Overview

Problem

Existing adhesives face challenges in achieving excellent adhesion to olefin-based resin materials like polyethylene and polypropylene due to their low surface energy, and the use of emulsifiers in self-emulsification type emulsions can leave residues that affect adhesion.

Innovation Solution

A self-emulsification type emulsion comprising a modified polypropylene resin with an anionic functional group and a tackifier, dispersed in water without an emulsifier, where the modified polypropylene resin surrounds the tackifier, forming fine particles for stable dispersion and improved adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If an emulsifier is used in self-emulsification type emulsion, then the polymer can be dispersed in water, but the emulsifier remains in the adhesive layer and adversely affects adhesion

Engineering Contradiction:
Improvedispersion stabilityVSAvoidadhesion quality
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent removes the emulsifier from the adhesive layer by using a self-emulsification type emulsion where the polymer itself serves as the emulsifier. The polymer contains hydrophilic polar groups that enable water dispersion without requiring external emulsifiers, thus eliminating the harmful residue that would otherwise remain in the adhesive layer and compromise adhesion quality.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The polymer is designed to perform dual functions: as the adhesive material and as its own emulsifier. The hydrophilic polar groups within the polymer chain enable self-emulsification, allowing the polymer to disperse in water without needing separate emulsifier additives. This self-service approach eliminates the need for external emulsifiers that would contaminate the adhesive layer.

Inventive Principle:
Principle #25Self-service

2Reliability

If corona discharge or plasma treatment is used to increase surface energy of olefin-based resin, then adhesion is improved, but expensive equipment is required and power consumption increases

Engineering Contradiction:
Improveadhesion qualityVSAvoidequipment complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a simple, cost-effective adhesive composition based on aqueous dispersion of polymer with hydrophilic polar groups. This approach replaces expensive corona discharge or plasma treatment equipment with a straightforward chemical formulation that achieves adhesion through the polymer's inherent properties, eliminating the need for complex surface treatment machinery.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the chemical parameters of the adhesive by incorporating polymers with specific hydrophilic polar groups (such as carboxyl, hydroxyl, or amine groups) that enable direct adhesion to olefin-based resins. This chemical parameter change allows adhesion without physical surface treatment, avoiding expensive equipment while maintaining effective bonding.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional organic solvent adhesives are used, then adhesion is achieved, but environmental friendliness is reduced

Engineering Contradiction:
Improveadhesion qualityVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces organic solvent-based adhesive systems with an aqueous dispersion system. The polymer is dispersed in water through self-emulsification, eliminating the need for organic solvents. This substitution maintains adhesive functionality while removing the environmental hazards associated with organic solvent vapor, flammability, and pollution.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent storage stability and adhesiveness to polyolefin-based resins with enhanced water resistance, eliminating the need for expensive equipment and reducing power consumption, while avoiding emulsifier residues in the adhesive layer.

Implementation Method 1

a self-emulsification type emulsion comprising a tackifier and a modified polypropylene resin having an anionic functional group, wherein (1) the modified polypropylene resin having an anionic functional group is dispersed in water in the absence of an emulsifier

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 2

a dispersion particle comprising the modified polypropylene resin having an anionic functional group includes the tackifier

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Data Source

PatentEP3196247B1Self-emulsification type emulsion containing modified polypropylene resin
Publication Date: 2022.03.23 TOYOBO CO LTD
  • EP3196247B1 patent drawing
  • EP3196247B1 patent drawing

AI summary

The present invention provides a self-emulsification type emulsion exhibiting excellent adhesion to olefin-based base materials such as polyethylene and polypropylene without using an emulsifier. The self-emulsification type emulsion of the present invention comprises a tackifier and a modified polypropylene resin having an anionic functional group, and satisfies (1) and (2) given below: (1) the modified polypropylene resin having an anionic functional group is dispersed in water in the absence of an emulsifier, and (2) a dispersion particle comprising the modified polypropylene resin having an anionic functional group surrounds the tackifier.