Self-Forming Nanogap Electrodes Using a SAM Release Layer

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Solution Overview

Problem

Existing methods for building solid state devices are limited in terms of cost and miniaturization, hindering the integration of RF components into everyday devices for the IoT ecosystem, and there is a need for scalable, cost-effective methods to create self-sustainable systems.

Innovation Solution

A method involving patterning a first metallic layer on a substrate, depositing a self-assembling monolayer, and forming a second metallic layer with a self-forming nanogap by removing overlapping parts using a SAM layer, allowing for the integration of conductive electrodes with nanoscale gaps, which can be filled with semiconductor or dielectric materials to form devices like transistors and diodes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing methods for building solid state devices are used, then manufacturing process is established, but manufacturing precision and miniaturization level are limited

Engineering Contradiction:
Improveminiaturization levelVSAvoidprocessing complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The SAM layer automatically performs the function of defining the nanogap boundaries and controlling the release of the second metallic layer. The self-assembling nature of the monolayer eliminates the need for complex external patterning processes, achieving sub-10nm precision without proportionally increasing process complexity

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The SAM layer acts as an intermediary between the first and second metallic layers, serving as both a deposition mask and a release agent. This intermediary enables precise nanogap formation through its self-assembling properties and selective adhesion characteristics

Inventive Principle:
Principle #24Intermediary (Mediator)

2Adaptability or versatility

If RF components are integrated into everyday devices, then functionality is improved, but manufacturing cost increases

Engineering Contradiction:
Improveintegration capabilityVSAvoidmanufacturing cost
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The device structure is segmented into distinct functional layers (first metallic layer, SAM layer, second metallic layer) that can be independently processed and optimized. This segmentation enables modular manufacturing approaches that reduce overall system cost while maintaining integration capability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The method changes the critical parameter from lithographic resolution (which is expensive at nanoscale) to SAM layer thickness and composition (which can be controlled chemically at lower cost). This parameter transformation enables cost-effective nanogap fabrication

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the fabrication of electronic devices with high yield and minimal complexity, allowing for efficient processing and integration of RF components into various substrates, including glass, plastic, and paper, with reduced operator involvement and cost-effective scalability.

Implementation Method 1

depositing a self-assembling monolayer, SAM, layer over and around the first electrode

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Data Source

PatentUS12382695B2Self-forming nanogap method and device
Publication Date: 2025.08.05 KING ABDULLAH UNIV OF SCI & TECH
  • US12382695B2 patent drawing
  • US12382695B2 patent drawing
  • US12382695B2 patent drawing

AI summary

A method for manufacturing a solid state device with a self-forming nanogap includes patterning a first metallic layer (M1) to form a first electrode on a substrate; depositing a self-assembling monolayer, SAM, layer over and around the first electrode; forming a second metallic layer (M2) in contact with the SAM layer and the substrate; and touchlessly removing parts of the second metallic layer (M2) that is formed directly above the SAM layer, to form a second electrode, and a nanogap between the first electrode and the second electrode.