Self-Healing Cementitious Mixtures with Calcium Compounds

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Solution Overview

Problem

Concrete structures deteriorate over time due to cracking, allowing harmful substances to penetrate and degrade the material, leading to potential collapse, and there is a need for self-healing and anti-corrosive building materials that provide shrinkage compensation.

Innovation Solution

A method of creating a cementitious mixture using a calcium compound, such as calcium oxide, in combination with ordinary Portland cement and supplementary cementitious materials, with specific dosage and particle size ranges, to produce a self-healing concrete with enhanced compressive strength and anti-corrosive properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional concrete is used, then construction is widely applicable, but the concrete deteriorates and cracks over time allowing harmful substances to penetrate

Engineering Contradiction:
Improveconcrete durabilityVSAvoidservice life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent incorporates calcium oxide and calcium hydroxide into the concrete mixture before casting, creating dormant healing agents that remain inactive during construction but become activated when cracks occur, allowing the concrete to heal itself automatically

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The concrete mixture contains self-healing components (calcium oxide, calcium hydroxide, and bacteria) that automatically detect and repair cracks without external intervention, enabling the material to maintain its own structural integrity over time

Inventive Principle:
Principle #25Self-service

2Reliability

If calcium compound is added to cementitious mixture, then self-healing capability is improved, but the mixture composition becomes more complex

Engineering Contradiction:
Improveself-healing capabilityVSAvoidmixture composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent specifies precise dosage ranges for calcium oxide (3.1-35% of total binder content) and calcium hydroxide (0.1-10% of total binder content) to optimize self-healing performance while maintaining manageable mixture complexity through quantitative control

Inventive Principle:
Principle #35Parameter changes

3Strength

If calcium compound is added to cementitious mixture, then compressive strength is enhanced, but manufacturing process becomes more complex

Engineering Contradiction:
Improvecompressive strengthVSAvoidmanufacturing process
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The calcium oxide and calcium hydroxide are pre-mixed with the cementitious materials before water addition, ensuring uniform distribution and simplifying the manufacturing process by incorporating the strength-enhancing agents into the base mixture rather than adding them separately during or after casting

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in concrete with improved self-healing capabilities, reduced shrinkage, and enhanced compressive strength, extending the lifespan of infrastructure while reducing maintenance and environmental impact.

Implementation Method 1

adding water to the cementitious mixture

Methodology Applied
Scientific EffectHydration reaction: Hydrolysis

Implementation Method 2

exhibits shrinkage compensation

Methodology Applied
Scientific EffectShrinkage compensation:

Data Source

PatentUS20240190769A1Building materials
Publication Date: 2024.06.13 DMAT SRL
  • US20240190769A1 patent drawing
  • US20240190769A1 patent drawing
  • US20240190769A1 patent drawing

AI summary

Disclosed herein are mixtures for cementitious building materials, methods of preparing same, and methods of cementing using same.