Self-Healing Dental Composite via Microcapsule Rupture

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Solution Overview

Problem

Dental composites have low resistance to disturbances such as cracks, fractures, and fissures, which can lead to partial or complete damage, and existing self-healing composites are not adequately effective in autonomically resolving these issues.

Innovation Solution

Incorporating additives, including monomers with alkoxy and vinyl groups, and catalysts like tin (II) ethylhexanoate within microcapsules in the dental restorative formulations, which rupture to initiate a self-healing reaction when disturbances occur, restoring the composite's integrity and morphology.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional dental composites are used, then the composite provides aesthetic appearance and basic structural properties, but the composite has low resistance to disturbances such as cracks, fractures, and fissures

Engineering Contradiction:
Improveresistance to disturbancesVSAvoidautonomous repair capability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent incorporates healing agents (monomers and catalysts) in microcapsules into the composite material before use. These microcapsules are distributed throughout the composite matrix in advance, positioned to rupture when cracks occur, automatically releasing healing agents to repair damage without external intervention

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The composite material is designed to self-heal through embedded microcapsules containing monomers and catalysts. When disturbances occur, the microcapsules rupture and the released components autonomously initiate polymerization reactions that repair cracks and fractures, enabling the material to service itself without external assistance

Inventive Principle:
Principle #25Self-service

2Strength

If the composite is made more resistant to disturbances through additional materials, then the strength improves, but the complexity of the formulation increases

Engineering Contradiction:
Improveresistance to disturbancesVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent uses microcapsules with flexible shells to encapsulate healing agents. These thin-film microcapsules are distributed throughout the composite and rupture upon mechanical disturbance, releasing the encapsulated monomers and catalysts. This approach integrates the healing function into the existing composite structure without requiring complex external systems

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent creates a multi-component composite system combining the base composite material with embedded microcapsules containing healing agents. This composite-of-composites approach integrates structural reinforcement and self-healing functionality into a single material system, managing complexity through hierarchical integration rather than separate components

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dental restorative formulations demonstrate improved resistance to disturbances, enabling autonomous repair and regeneration of dental structures, maintaining functionality and morphology, and are biocompatible with minimal wear over time.

Implementation Method 1

the catalyst initiates a polymerization reaction between the monomers with alkoxy and vinyl groups

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS9763858B2Self-healing dental restorative formulations and related methods
Publication Date: 2017.09.19 PREMIER DENTAL PRODUCTS CO LLC
  • US9763858B2 patent drawing
  • US9763858B2 patent drawing
  • US9763858B2 patent drawing

AI summary

Dental restorative formulations comprising an additive material and a capsule incorporated into the continuous phase of a dental material. The additive material includes one or more alkoxy groups and one or more vinyl groups. The capsule includes a catalyst and a molecule with one or more silanol groups. The dental restorative formulation is applied and polymerized to form a composite. When a disturbance occurs in the dental composite, the capsule ruptures so that the catalyst initiates a condensation reaction between the molecule with one or more silanol groups and the one or more alkoxy groups thereby healing the dental composite.