Self-Limiting Electrospray Deposition for Uniform 3D Coatings

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Solution Overview

Problem

Existing coating technologies face challenges in achieving a self-limiting thickness for electrospray deposition, leading to wasted material mass and inefficiencies in applying thin, functional coatings on complex surfaces.

Innovation Solution

The development of a self-limiting electrospray composition that includes a non-charge-dissipative component and a charge-dissipative component, allowing for the formation of a layer with a self-limiting thickness that hinders further accumulation of the spray on conductive targets.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If conventional electrospray deposition is used without thickness control mechanisms, then material mass is wasted due to excessive coating thickness, but achieving self-limiting thickness requires additional control mechanisms

Engineering Contradiction:
Improvematerial mass wasteVSAvoiddeposition control mechanism
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The coating composition itself provides the thickness control mechanism through its inherent properties. The non-charge-dissipative component automatically limits further deposition when a sufficient layer forms, eliminating the need for external control systems. This self-regulating mechanism resolves the contradiction by making the coating system self-managing.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention changes the electrical parameters of the coating composition by introducing components with different charge dissipation characteristics. This parameter change enables the coating to naturally regulate its own thickness through controlled charge accumulation and dissipation cycles, resolving the thickness control issue without additional device complexity.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If molecular deposition techniques are used to achieve thin coatings, then coating precision is improved, but the process requires high-vacuum or fluid bath conditions increasing complexity and cost

Engineering Contradiction:
Improvecoating thickness precisionVSAvoidprocess requirements
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention replaces complex mechanical vacuum or fluid bath systems with a simpler electrostatic field-based process. The self-limiting electrospray composition uses electrical charge properties to achieve precise thickness control in ambient conditions, substituting complex mechanical containment systems with a more straightforward electrostatic mechanism.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of operation

If condensed deposition techniques are used for spray coating, then ease of operation is improved, but capillary or shadowing effects occur on 3D surfaces reducing uniformity

Engineering Contradiction:
Improvespray coating simplicityVSAvoidcoating uniformity on 3D surfaces
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The self-limiting electrospray composition provides real-time feedback through charge accumulation. As the coating thickness increases, charge builds up and automatically repels further deposition, creating a self-regulating feedback loop that ensures uniform thickness even on complex 3D surfaces without requiring precise external control.

Inventive Principle:
Principle #23Feedback

4Loss of substance

If thin functional coatings are applied to maximize material efficiency, then material cost is reduced, but coating adhesion and uniformity become more difficult to achieve

Engineering Contradiction:
Improvematerial efficiencyVSAvoidcoating adhesion
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The invention changes the electrical and chemical parameters of the coating composition to optimize both thinness and adhesion. By controlling charge dissipation and incorporating specific polymer components, the coating achieves optimal properties at minimal thickness, resolving the contradiction between material efficiency and coating reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces material waste by ensuring only a thin, well-adhered coating is applied, while also enabling the deposition of coatings on complex 3D surfaces with uniform thickness and high efficiency.

Implementation Method 1

a non-charge-dissipative component and a charge-dissipative component... allowing for the formation of a layer with a self-limiting thickness that hinders further accumulation of the spray

Methodology Applied
Scientific EffectElectrostatic charge accumulation: Electrostatics

Implementation Method 2

the layer with a self-limiting thickness that hinders further accumulation of the spray on conductive targets

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 3

a self-limiting electrospray composition including a non-charge-dissipative component and a charge-dissipative component

Methodology Applied
Scientific EffectCharge dissipation: Electrostatics

Data Source

PatentUS12343935B2Thickness-limited electrospray deposition
Publication Date: 2025.07.01 RUTGERS THE STATE UNIV
  • US12343935B2 patent drawing
  • US12343935B2 patent drawing
  • US12343935B2 patent drawing

AI summary

Self-limiting electrospray compositions including a non-charge-dissipative component and/or a charge-dissipative component. Self-limiting electrospray composition including a plurality of charge-dissipative components and excluding a non-charge-dissipative component. Methods for forming layers of self-limiting thickness. Methods for determining a conductivity of a material. Methods for repairing a flaw in a layer on a surface of an object.