Self-Spreading Biocide via Silicone Spreading

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Solution Overview

Problem

Current decontamination methods are inefficient for inaccessible surfaces and require unstable chemical agents, often leading to incomplete disinfection and safety concerns, with existing self-disinfecting technologies being difficult to apply and lacking mobility.

Innovation Solution

Development of a highly-mobile, self-spreading biocide system combining polydimethylsiloxane (PDMS) with quaternary ammonium salts or phenol biocidal moieties, allowing for facile application and effective coverage of surfaces, including those hard to reach, by leveraging the spreading properties of silicone fluids and antimicrobial properties of these compounds.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional decontaminating agents are used, then decontamination can be achieved, but the agents are unstable and require activation just prior to use, losing effectiveness within hours

Engineering Contradiction:
Improvedecontamination effectivenessVSAvoidchemical agent stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The biocidal agent is pre-applied to surfaces during manufacturing or installation, allowing it to be present and active before contamination occurs. This eliminates the need for activation just prior to use and prevents degradation over time, as the agent is already in its effective form on the surface.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The self-spreading biocidal composition automatically activates and distributes itself upon contact with contaminated surfaces, requiring no external activation or reapplication. The composition self-regulates its distribution and maintains effectiveness continuously, eliminating the need for periodic reactivation.

Inventive Principle:
Principle #25Self-service

2Reliability

If decontaminating agents are transported to contaminated areas, then decontamination can be performed, but tons of agents and solvents must be transported, making the process complex and resource-intensive

Engineering Contradiction:
Improvedecontamination capabilityVSAvoidlogistics complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The biocidal composition is applied to surfaces during manufacturing or installation, eliminating the need for subsequent transportation and application of large quantities of agents. The surface itself becomes the decontamination device, requiring no complex logistics for agent delivery.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The treated surface automatically neutralizes contaminants upon contact, requiring no external decontamination equipment, personnel, or logistics. The surface performs self-decontamination, eliminating the need for transporting agents to contaminated areas.

Inventive Principle:
Principle #25Self-service

3Ease of operation

If moisture is used for distribution of biocides, then distribution can be achieved, but efficacy is rapidly attenuated by organic matter and moisture alone results in mold and bacteria growth

Engineering Contradiction:
Improvebiocide distributionVSAvoidmold and bacteria growth
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The biocidal composition combines hydrophilic biocidal agents with hydrophobic silicone-based carriers, creating a composite material that leverages the water-attracting properties for distribution while the hydrophobic matrix prevents excessive moisture retention that would promote mold and bacterial growth.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The composition provides different functional properties in different phases: the hydrophilic components facilitate distribution and contact with contaminants, while the hydrophobic silicone base prevents water accumulation and mold growth, creating localized functional zones within the same material.

Inventive Principle:
Principle #3Local quality

4Area of stationary object

If self-spreading biocidal compositions are applied to surfaces, then effective coverage including inaccessible surfaces can be achieved, but the composition must maintain stability and effectiveness over long periods

Engineering Contradiction:
Improvesurface coverage areaVSAvoidself-disinfection duration
Core Design Contradiction:
Area of stationary objectVSDuration of action of stationary object

Solution Approach 1:

The silicone-based composite material provides both the self-spreading capability needed for extensive surface coverage and the chemical stability required for long-term effectiveness. The hydrophobic silicone matrix protects the biocidal agents from degradation while allowing controlled distribution across surfaces.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Instead of using volatile or unstable agents that require frequent reapplication, the invention uses stable, non-volatile silicone-based compositions that remain effective indefinitely once applied, inverting the traditional approach where stability compromises spreading ability.

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The biocide system effectively neutralizes pathogens on contact, providing long-term self-disinfection capabilities with minimal application, suitable for various surfaces and environments, including air ducts and electronic apparatus, while maintaining antimicrobial activity against both Gram-positive and Gram-negative bacteria.

Implementation Method 1

The biocidal composition is capable of self-spreading upon application to a surface

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

leveraging the spreading properties of silicone fluids

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 3

The compounds neutralize pathogens on contact and exhibit long term self-disinfection capabilities... maintaining antimicrobial activity against both Gram-positive and Gram-negative bacteria

Methodology Applied
Scientific EffectCell membrane disruption:

Data Source

PatentUS8653293B2Mobile self-spreading biocides
Publication Date: 2014.02.18 THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE NAVY
  • US8653293B2 patent drawing
  • US8653293B2 patent drawing
  • US8653293B2 patent drawing

AI summary

A compound having the formula:Each R1 is C1-C3 alkyl group or fluoridated C1-C3 alkyl group. The value n is a positive integer. Each R2 is alkylene group or polyethylene glycol group. Y1 is hydrogen, quaternary ammonium containing group, or phenol-containing group. Y2 is quaternary ammonium-containing group or phenol-containing group. The quaternary ammonium-containing group is non-aromatic and contains no more than one quaternary ammonium.