Ringing gel composition

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Solution Overview

Problem

Existing fragrance delivery systems in consumer products face challenges in achieving long-lasting fragrance performance and stable suspension of microcapsules, particularly due to low Newtonian viscosity and compatibility issues with charged surfactants, which limit their application across various substrates.

Innovation Solution

A self-thickened ringing gel composition with a viscoelastic behavior and viscosity between 0.1 and 1000 Pa.s at 0.01 s^-1 shear rate, comprising an aqueous phase, a non-ionic surfactant system with a mean HLB between 10 and 14, and an oil phase with a hydrophobic active ingredient, capable of suspending microcapsules without sedimentation and requiring no external thickener.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If microemulsion systems are used for fragrance delivery, then fragrance solubilisation is improved, but microcapsule suspension stability deteriorates due to low Newtonian viscosity

Engineering Contradiction:
Improvefragrance solubilisationVSAvoidmicrocapsule suspension stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent changes the rheological parameters of the formulation by incorporating viscoelastic polymers that modify the viscosity profile. The system transitions from a purely Newtonian low-viscosity microemulsion to a non-Newtonian formulation with shear-thinning behavior and enhanced low-shear viscosity, enabling microcapsule suspension while preserving fragrance solubilisation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite system combining microemulsion components (surfactants, oils, water) with viscoelastic polymer networks. This composite structure provides dual functionality: the microemulsion phase solubilizes fragrance while the polymer network provides structural support for microcapsule suspension

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If external thickeners are used to achieve stable microcapsule suspension, then suspension stability is improved, but formulation complexity and compatibility issues increase

Engineering Contradiction:
Improvemicrocapsule suspension stabilityVSAvoidformulation complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent merges the thickening function with the existing surfactant and polymer components already present in the microemulsion formulation. Rather than adding separate external thickeners, the system utilizes the synergistic interactions between surfactants and polymers to generate the required viscoelasticity and suspension stability

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The formulation components themselves (surfactants and polymers) provide the thickening and suspension-stabilizing functions inherently, without requiring additional external thickening agents. The system self-organizes to provide the necessary structural properties through component interactions

Inventive Principle:
Principle #25Self-service

3Stability of the object's composition

If lyotropic liquid crystalline phases are used for microcapsule suspension, then suspension stability is improved, but viscosity becomes excessively high requiring high energy shearing

Engineering Contradiction:
Improvemicrocapsule suspension stabilityVSAvoidshearing energy
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The patent modifies the viscosity parameters by creating a non-Newtonian shear-thinning system rather than using high-viscosity Newtonian liquid crystals. The formulation exhibits low viscosity at high shear rates (facilitating mixing and application) while maintaining high viscosity at low shear rates (providing suspension stability)

Inventive Principle:
Principle #35Parameter changes

4Stability of the object's composition

If charged surfactants are used in the formulation, then microcapsule suspension is improved, but compatibility with consumer products deteriorates

Engineering Contradiction:
Improvemicrocapsule suspensionVSAvoidproduct compatibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent uses non-ionic surfactants as intermediary agents that provide steric stabilization for microcapsule suspension without the electrostatic interactions that cause compatibility issues. These surfactants act as mediators between the microcapsules and the consumer product matrix, enabling stable suspension while maintaining broad compatibility

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ringing gel composition enhances fragrance deposition and retention on substrates, providing stable suspension of microcapsules and improved fragrance performance compared to microemulsion systems, while maintaining low viscosity and compatibility with different consumer products.

Implementation Method 1

a non-ionic surfactant system with a mean HLB between 10 and 14

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

a self-thickened ringing gel composition with a viscoelastic behavior and viscosity between 0.1 and 1000 Pa.s

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

an oil phase comprising a hydrophobic active ingredient

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Data Source

PatentEP3528902B1Ringing gel composition
Publication Date: 2021.03.31 FIRMENICH SA
  • EP3528902B1 patent drawingFigure 1a~1b
  • EP3528902B1 patent drawingFigure 2~3
  • EP3528902B1 patent drawingFigure 4(a)~4(b)

AI summary

The present invention relates to the field of liquid solubilizing systems. More specifically, the present invention relates to a ringing gel composition i.e. a self-thickened composition having a viscoelastic behavior and a viscosity comprised between 0.1 and 1000 Pa.s at 20°C at 0.01 s-1 shear rate, said ringing gel comprising an aqueous phase, a surfactant system essentially consisting of non-ionic surfactant(s), a linker and an oil phase comprising an hydrophobic active ingredient, preferably a perfume. Consumer products comprising said ringing gel composition, such as a self-thickened liquid laundry scent booster are also part of the present invention.