SEM Charging and EFISH for Wafer Interface Trap Density

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Solution Overview

Problem

Current semiconductor wafer testing methods face challenges in non-invasively and non-destructively measuring electrical properties, such as dielectric properties and charge carrier lifetime, due to issues with charge distribution and surface contamination, which affect the accuracy and reliability of measurements.

Innovation Solution

The use of a scanning electron microscope (SEM) to deposit charge on the wafer surface and a pulsed laser for second harmonic generation (SHG) measurements, allowing for contactless and non-invasive determination of electrical properties by analyzing the SHG signal, while maintaining the wafer in a vacuum to minimize contamination and charge diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional contact-based measurement methods are used to determine electrical properties, then measurement accuracy can be improved, but the wafer surface becomes contaminated and charge distribution is disturbed

Engineering Contradiction:
Improveelectrical property measurement accuracyVSAvoidwafer surface contamination and charge distribution disturbance
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent replaces mechanical contact-based measurement systems with a non-contact optical system. A probe laser beam is directed at the wafer surface to induce second harmonic generation, and the reflected light is detected to determine electrical properties such as interface state density and charge carrier lifetime. This substitution eliminates physical contact, thereby preventing surface contamination and charge distribution disturbance while maintaining measurement accuracy.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces light as an intermediary medium to transfer information from the wafer surface without direct contact. The probe laser beam interacts with the wafer surface to generate second harmonic signals that carry information about electrical properties. This intermediary approach allows measurement of electrical characteristics while avoiding the harmful effects of direct contact, including contamination and charge disturbance.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Adaptability or versatility

If invasive scribing or grounding methods are used to enable measurement, then measurement capability is improved, but the wafer structure is damaged and processing complexity increases

Engineering Contradiction:
Improvemeasurement capabilityVSAvoidprocessing complexity and wafer damage
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent replaces invasive mechanical preparation methods (scribing, grounding) with non-contact optical measurement. The probe laser beam can measure electrical properties on intact wafer surfaces without requiring any physical modification. This eliminates the need for complex preparatory steps and preserves wafer structure, thereby reducing processing complexity while maintaining full measurement capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent performs measurement actions before any invasive preparation would be needed. By using non-contact optical measurement on the as-received wafer surface, the system obtains electrical property data without requiring subsequent scribing or grounding steps. This preliminary measurement approach eliminates the need for additional processing complexity and preserves wafer integrity.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If the wafer is exposed to ambient environment during measurement, then ease of operation is improved, but charge diffusion and measurement reliability deteriorate

Engineering Contradiction:
Improvemeasurement accessibilityVSAvoidcharge distribution stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent employs a vacuum environment as an inert atmosphere during measurement. The vacuum chamber prevents ambient air molecules from interacting with the wafer surface, thereby eliminating charge diffusion caused by air exposure. This controlled environment maintains charge distribution stability and measurement reliability while the non-contact optical method ensures ease of operation by requiring no special wafer preparation for vacuum compatibility.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The non-contact optical measurement system allows measurements to be performed through the vacuum chamber window without breaking vacuum. The probe laser beam and detection system can operate remotely, maintaining the vacuum environment throughout the measurement process. This substitution of contact-based methods with optical methods enables the vacuum environment to be maintained, ensuring charge stability while preserving operational ease.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables precise and accurate measurement of electrical properties without damaging the wafer, reducing measurement errors and allowing for in-line testing during front-end-of-line (FEOL) processing, with the ability to determine interface state density and charge distribution without invasive scribing or grounding.

Implementation Method 1

using a scanning electron microscope (SEM) or components typically used in an SEM (e.g., electron gun, anode, electron lenses, electron beam deflector) to deposit charge on a top surface of an insulator layer

Methodology Applied
Scientific EffectElectron beam charging: Electron Beam

Implementation Method 2

measuring an optical response of the semiconductor wafer. This optical response may comprise, for example, second harmonic generation (SHG) light having a frequency that is the second harmonic of the frequency of incident pulsed laser light

Methodology Applied
Scientific EffectSecond harmonic generation: Second Harmonic Generation

Implementation Method 3

in various implementations the Electric Field Induced Second Harmonic generation (EFISH) is measured in response to SHG laser stimulus with the addition of surface charge provided by an SEM or SEM components

Methodology Applied
Scientific EffectElectric field induced second harmonic generation:

Data Source

PatentUS20240071710A1Method and apparatus for non-invasive semiconductor technique for measuring dielectric/semiconductor interface trap density using scanning electron microscope charging
Publication Date: 2024.02.29 FEMTOMETRIX INC
  • US20240071710A1 patent drawing
  • US20240071710A1 patent drawing
  • US20240071710A1 patent drawing

AI summary

A non-invasive semiconductor technique for measuring dielectric/semiconductor interface trap density can be performed by charging the dielectric by creating charges on the top surface of the dielectric layer over the wafer using Scanning Electron Microscope (SEM) charging. This charging can induce an accumulated, a depleted and/or an inverted semiconductor surface. The states of the semiconductor surface can subsequently be measured, identified, and/or quantified using Electric Field Induced Second Harmonic generation (EFISH). From the measured/acquired EFISH versus SEM charge curve, the interface state density (Dit) can be extracted. A large working distance provides the ability to create charge and measure the Second Harmonic Generation (SHG) at the same semiconductor surface spot without the needing to move the wafer.