Semi-IPN Polymer Electrolyte for Strength-Conductivity Balance
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Solution Overview
Problem
Existing solid polymer electrolytes for lithium secondary batteries face challenges in achieving both high mechanical strength and high ionic conductivity, which are essential for commercialization and efficient battery performance.
Innovation Solution
A polymer electrolyte is developed using a semi-interpenetrating polymer network (semi-IPN) structure, comprising a first polymer with a specific repeating unit and a second polymer derived from a monomer with ethylenically unsaturated groups, along with a lithium salt, to enhance mechanical strength and ion transfer capability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If polyethylene oxide is used as the polymer electrolyte to achieve high ionic conductivity, then ion transfer capability is improved, but mechanical strength deteriorates due to semi-crystalline structure
Solution Approach 1:
The patent employs a composite polymer electrolyte system combining polyethylene oxide (PEO) with a crosslinking agent. The PEO provides ionic conductivity through its crystalline structure, while the crosslinking agent forms a three-dimensional network that reinforces mechanical strength. This composite approach allows both functions to coexist: the PEO chains maintain ion transport pathways while the crosslinked structure prevents mechanical degradation.
Solution Approach 2:
The patent modifies the physical and chemical parameters of the polymer electrolyte by introducing crosslinking. The crosslinking degree and network density are controlled to optimize the balance between mechanical strength and ionic conductivity. By adjusting crosslinking parameters, the material transitions from a purely semi-crystalline structure to a crosslinked semi-crystalline structure with enhanced mechanical properties while preserving ion transfer capability.
2Strength
If crosslinking is introduced to improve mechanical strength, then structural integrity is improved, but ion transfer capability may be hindered
Solution Approach 1:
The patent carefully controls the crosslinking parameters including crosslinking agent concentration, crosslinking density, and network structure. By optimizing these parameters, the crosslinked structure provides mechanical strength without creating excessive barriers to ion transport. The crosslinking is designed to be sparse enough to allow ion pathways while dense enough to provide structural integrity.
Solution Approach 2:
The crosslinking is distributed throughout the polymer matrix in a controlled manner, creating local regions of enhanced mechanical strength while maintaining overall ion transfer pathways. The crosslinked network provides structural support in specific regions without completely blocking the ion transport channels that run through the polymer electrolyte.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The proposed polymer electrolyte achieves excellent mechanical strength and maintains high ionic conductivity, leading to improved electrochemical stability at high voltage and high temperature, thus enabling the development of high-performance lithium secondary batteries.
Implementation Method 1
ion transfer capability is improved
Data Source
AI summary
The present invention relates to a polymer electrolyte for a secondary battery and a lithium secondary battery including the same, and to a polymer electrolyte for a secondary battery, which includes a first polymer including a repeating unit represented by Formula 1, and a second polymer including a repeating unit derived from a monomer having at least one ethylenically unsaturated group or an oligomer thereof, and a lithium secondary battery including the same.


