Semi-permeable Container Top for Ascorbic Acid Degradation Venting

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Solution Overview

Problem

Ascorbic acid is unstable in solutions, particularly degrading into carbon dioxide, which leads to packaging issues such as pressure buildup and premature failure, especially when exposed to higher temperatures, and existing methods like oxygen reduction or scavengers are insufficient to prevent degradation.

Innovation Solution

Using a semi-permeable container top, such as a silicone bulb or stopper, to allow carbon dioxide venting during ascorbic acid degradation, thereby preventing excess pressure and package failure, while maintaining the impermeable nature of the container to prevent oxygen exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If air tight containers with impermeable materials are used to prevent oxygen from degrading ascorbic acid, then oxidation protection is improved, but carbon dioxide buildup causes package failure and foaming

Engineering Contradiction:
Improveoxygen exposureVSAvoidcarbon dioxide buildup
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent employs a semi-permeable membrane that allows carbon dioxide to pass through while blocking oxygen. This selective permeability resolves the contradiction by permitting the harmful byproduct (CO2) to escape while preventing the harmful reactant (O2) from entering and degrading the ascorbic acid.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The semi-permeable membrane acts as an intermediary between the ascorbic acid composition and the external environment. It selectively mediates gas exchange by allowing CO2 to pass through while blocking O2, thus resolving the contradiction between preventing oxidation and allowing CO2 venting.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If oxygen scavengers are added to prevent ascorbic acid degradation, then oxidation protection is improved, but carbon dioxide generation still causes package pressurization

Engineering Contradiction:
ImproveoxidationVSAvoidpackage pressurization
Core Design Contradiction:
Object-affected harmful factorsVSStress or pressure

Solution Approach 1:

The semi-permeable membrane serves as an intermediary that allows CO2 to escape from the package while preventing O2 from entering. This resolves the contradiction by providing a pathway for pressure relief without compromising the oxidation protection provided by oxygen scavengers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent extracts the carbon dioxide gas from the package through the semi-permeable membrane, removing the harmful byproduct that causes pressurization while maintaining the internal environment protected from oxygen.

Inventive Principle:
Principle #2Taking out (Extraction)

3Stability of the object's composition

If refrigeration is used to slow ascorbic acid degradation, then degradation rate is reduced, but shipping and storage complexity increases

Engineering Contradiction:
Improveascorbic acid stabilityVSAvoidstorage and shipping requirements
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The semi-permeable membrane package provides self-service by automatically regulating gas exchange without requiring external temperature control. The membrane passively allows CO2 to escape and O2 to be blocked, enabling the product to maintain stability during shipping and storage without refrigeration infrastructure.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent changes the permeability parameters of the packaging material to create a semi-permeable membrane with selective gas transmission properties. This parameter change allows the package to function without temperature control by inherently managing gas exchange based on molecular size and solubility differences between CO2 and O2.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The semi-permeable container top effectively reduces carbon dioxide buildup, preventing package pressurization and extending the shelf life of ascorbic acid-containing compositions without significantly affecting the degradation rate of ascorbic acid, thus maintaining product integrity and usability.

Implementation Method 1

packaging the composition in a container having a semi-permeable container top

Methodology Applied
Scientific EffectSemipermeable Membrane: Semipermeable Membrane

Data Source

PatentUS10155610B2Method of controlling by-products of vitamin C degradation and improving package integrity shelf life
Publication Date: 2018.12.18 PHILIP J GORDON CONSULTANTS
  • US10155610B2 patent drawing
  • US10155610B2 patent drawing
  • US10155610B2 patent drawing

AI summary

The invention is a method of venting the degradation products of an ascorbic acid containing composition. This prevents a build-up of carbon dioxide and may prolong the life of the packaging. The packaging includes an impermeable container and a semi-permeable top, which allows carbon dioxide to vent over time. When the composition includes water, the surface area of semi-permeable material contacting the composition is reduced to lessen water vapor loss.