Semiconductor Atomic Layer Etch for High-Selectivity Pattern Uniformity

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Solution Overview

Problem

Current etch processes in semiconductor manufacturing, such as reactive ion etch (RIE), face challenges with loading effects, selectivity, and uniformity, leading to defects like film residues and corner rounding, which impact product yield and reliability.

Innovation Solution

An apparatus and method for conducting high-selectivity atomic layer etch (ALE) using an ionizer and implanter to generate low-energy charged particles and reactive ions, which selectively remove atoms from a substrate's surface without damaging underlying layers by forming compounds with ionized etchants and sputtering them with particles of controlled energy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If reactive ion etch (RIE) is used for directional patterning, then etching capability is improved, but loading effect and selectivity deteriorate causing poor uniformity

Engineering Contradiction:
Improveetching capabilityVSAvoidpattern uniformity
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The etching process is divided into two distinct stages: a first etching process that removes the majority of the film thickness, and a second etching process that completes the pattern formation. This segmentation allows each process to be optimized independently - the first process handles bulk removal efficiently while the second process achieves precise pattern definition with high uniformity, thereby resolving the contradiction between etching speed and pattern uniformity.

Inventive Principle:
Principle #1Segmentation

2Productivity

If high energy particles are used for etching, then etching rate is improved, but damage to underlying layers increases

Engineering Contradiction:
Improveetching rateVSAvoidsubstrate damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent employs parameter changes by adjusting particle energy across different etching stages. High energy particles are used in the first etching process to achieve high etching rates, while low energy particles are used in the second etching process to minimize substrate damage. This dynamic parameter adjustment allows the system to achieve both high productivity and low harmful effects at different stages of the process.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional etch processes are used, then manufacturing speed is maintained, but defect rate increases due to film residues and corner rounding

Engineering Contradiction:
Improvemanufacturing speedVSAvoidproduct yield
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The first etching process acts as a preliminary action that removes the bulk of the film material before the second precise etching process. By performing this preliminary removal, the subsequent second etching process operates on a reduced thickness with lower energy particles, which prevents corner rounding and film residue formation. This preliminary action maintains manufacturing speed while significantly improving product yield and reliability.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves precise and uniform pattern definition with high selectivity, reducing defects and improving the reliability and yield of semiconductor manufacturing by controlling the energy distribution of charged particles to avoid damage to underlying layers.

Implementation Method 1

An etchant is generated by an ionizer

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 2

The compound is removed by bombarding the compound with the particle

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS11908700B2Method for manufacturing semiconductor structure
Publication Date: 2024.02.20 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11908700B2 patent drawing
  • US11908700B2 patent drawing
  • US11908700B2 patent drawing

AI summary

In some embodiments of the present disclosure, a method of manufacturing a semiconductor structure includes the following operations. A substrate including a first atom and a second atom is provided. An etchant is dispatched from an ionizer. A compound is formed over the substrate by bonding the first atom with the etchant. A particle is released from an implanter. The compound is removed by bombarding the compound with the particle having an energy smaller than a bonding energy between the first atom and the second atom, wherein the particle is different from the etchant.