Semiconductor Capacitor Metal Layer for Hydrogen Sintering

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Solution Overview

Problem

In semiconductor device manufacturing, the tungsten layer acts as a barrier to hydrogen penetration during hydrogen sintering, reducing electrical performance, and omitting it leads to poor uniformity and increased resistance between contact and electrode.

Innovation Solution

A semiconductor device design where a metal layer is partially exposed over a conductive layer, allowing smooth hydrogen sintering and serving as an etching stop layer, maintaining conductive layer thickness and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a tungsten layer is added to the upper electrode to serve as an etching stop layer, then the etching control is improved, but the hydrogen sintering treatment is hindered due to the barrier effect

Engineering Contradiction:
Improveetching controlVSAvoidelectrical performance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent extracts the etching stop layer function from the tungsten layer and assigns it to a separate dedicated etching stop layer. This allows the upper electrode to be composed of only the conductive layer and metal layer, removing the hydrogen barrier while preserving etching control through the dedicated stop layer.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent segments the functions of the upper electrode by separating the etching stop layer from the conductive layers. The upper electrode consists of a conductive layer (boron-doped silicon germanium) and a metal layer, while the etching stop layer is a separate component, allowing each layer to optimize its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

2Reliability

If the tungsten layer is omitted to enable hydrogen sintering, then the hydrogen penetration is improved, but the thickness of the conductive layer must be increased which reduces uniformity

Engineering Contradiction:
Improveelectrical performanceVSAvoiduniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent extracts the etching stop layer function from the tungsten layer and assigns it to a separate dedicated etching stop layer. This allows the upper electrode to be composed of only the conductive layer and metal layer, removing the hydrogen barrier while preserving etching control through the dedicated stop layer.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent segments the functions of the upper electrode by separating the etching stop layer from the conductive layers. The upper electrode consists of a conductive layer (boron-doped silicon germanium) and a metal layer, while the etching stop layer is a separate component, allowing each layer to optimize its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

3Reliability

If the tungsten layer is omitted from the upper electrode, then the hydrogen sintering is improved, but the resistance between contact and electrode increases

Engineering Contradiction:
Improveelectrical performanceVSAvoidcontact resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material composition and structure of the upper electrode by introducing a metal layer (such as copper or cobalt) with superior electrical conductivity. This metal layer is formed on the conductive layer and provides a low-resistance path for electrical connection, reducing the contact resistance between the contact plug and the upper electrode while allowing the conductive layer to maintain optimal thickness for hydrogen sintering.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves electrical performance by enabling effective hydrogen sintering and reducing contact resistance through better uniformity and etching control.

Implementation Method 1

the metal layer exposes a portion of the first conductive layer, that is, the metal layer does not completely cover the first conductive layer, the subsequent hydrogen sintering treatment can be smoothly performed

Methodology Applied
Scientific EffectHydrogen penetration: Permeation

Implementation Method 2

since the metal layer can be used as an etching stop layer in the subsequent contact formation process

Methodology Applied
Scientific EffectEtching stop:

Implementation Method 3

the hydrogen sintering (H2 sintering) treatment is used to reduce dangling bonds to improve the electrical performance of the semiconductor device

Methodology Applied
Scientific EffectHydrogen sintering: Sintering

Data Source

PatentUS11393821B1Semiconductor device and manufacturing method thereof
Publication Date: 2022.07.19 WINBOND ELECTRONICS CORP
  • US11393821B1 patent drawing
  • US11393821B1 patent drawing
  • US11393821B1 patent drawing

AI summary

A semiconductor device including a substrate and a capacitor is provided. The substrate includes a memory array region. The capacitor is located in the memory array region. The capacitor includes a first electrode, a second electrode, and an insulating layer. The first electrode is located on the substrate. The second electrode includes a first conductive layer and a metal layer. The first conductive layer is located on the first electrode. The metal layer is located on the first conductive layer. The metal layer exposes a portion of the first conductive layer. The insulating layer is located between the first electrode and the second electrode.