Semiconductor Copper Interconnect Metal Cap Layer Electromigration

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Solution Overview

Problem

Copper interconnections in semiconductor structures face electromigration issues due to high migration mobility of copper atoms, leading to device instability and increased leakage current, which existing methods fail to adequately address.

Innovation Solution

A semiconductor fabrication method involving the formation of a metal barrier layer with a dense texture and uniform thickness on top of a copper metal layer, followed by conversion into a self-aligned metal cap layer using a silicon-containing gas, to prevent copper and silicon atom diffusion and enhance electromigration resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If copper interconnection is used to replace aluminum interconnection, then electrical resistivity is reduced and electromigration resistance is improved, but copper atom diffusion into silicon and dielectric materials increases causing device instability

Engineering Contradiction:
Improveelectromigration resistanceVSAvoidcopper atom diffusion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A metal barrier layer is introduced as an intermediary between the copper interconnection layer and the silicon/dielectric materials. This barrier layer prevents copper atoms from diffusing into the substrate while maintaining the low resistivity and electromigration resistance benefits of copper interconnections.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent uses a composite structure combining copper interconnection layer with a metal barrier layer. The composite material approach allows the system to benefit from copper's excellent electrical properties while the barrier layer provides protection against copper diffusion, resolving the contradiction between reliability improvement and harmful diffusion effects.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If copper atoms diffuse into semiconductor substrate or dielectric layer, then electromigration increases causing circuit failure, but the metal barrier layer needs to be dense and uniform to prevent this diffusion

Engineering Contradiction:
ImproveelectromigrationVSAvoidmetal barrier layer uniformity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The metal barrier layer is formed in advance before the copper interconnection layer is deposited. This preliminary action ensures that the barrier layer is already in place to prevent copper diffusion, and its uniformity is established before subsequent processing steps that might affect the copper layer.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent optimizes the parameters of the metal barrier layer including its thickness, composition, and density to achieve the right balance between preventing copper diffusion and maintaining manufacturability. By carefully controlling these parameters, the barrier layer becomes dense and uniform enough to prevent electromigration while remaining feasible to manufacture.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If a metal barrier layer is formed to prevent copper diffusion, then electromigration resistance is improved, but the fabrication process complexity increases

Engineering Contradiction:
Improveelectromigration resistanceVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The formation of the metal barrier layer is merged with existing fabrication process steps such as sputtering or atomic layer deposition that are already used for other layers in the semiconductor structure. This integration reduces the overall process complexity by combining multiple functions into established process flows rather than introducing entirely new manufacturing steps.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively reduces electromigration and electrical resistance issues in semiconductor structures by forming a dense and uniform metal cap layer that prevents copper atom migration and silicon atom diffusion, thereby improving the reliability and performance of the semiconductor structure.

Implementation Method 1

converting the metal barrier layer to a metal cap layer by introducing a silicon-containing gas onto a surface of the metal barrier layer

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

removing the portion of the metal layer formed above the top surface of the dielectric layer by polishing

Methodology Applied
Scientific EffectMechanical Abrasion: Abrasion

Implementation Method 3

removing the metal oxide layer from the top surface of the metal layer

Methodology Applied
Scientific EffectChemical Etching:

Data Source

PatentUS9852991B2Semiconductor structure and fabrication method thereof
Publication Date: 2017.12.26 SEMICON MFG INT (SHANGHAI) CORP
  • US9852991B2 patent drawing
  • US9852991B2 patent drawing
  • US9852991B2 patent drawing

AI summary

A method for fabricating a semiconductor structure includes providing a dielectric layer on a semiconductor substrate, forming an opening in the dielectric layer to expose a portion of the surface of the semiconductor substrate, forming a metal layer to fill up the opening, and removing the portion of the metal layer formed above the top surface of the dielectric layer by polishing. A metal oxide layer is formed on the surface of the metal layer after polishing. The method further includes removing the metal oxide layer from the top surface of the metal layer, forming a metal barrier layer on the top surface of the metal layer after the removal of the metal oxide layer to provide a more uniform thickness and a denser texture, and converting the metal barrier layer to a metal cap layer by introducing a silicon-containing gas onto a surface of the metal barrier layer.