Semiconductor Thin Film Crystallization via Metal Element Transfer

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Solution Overview

Problem

Existing methods for manufacturing crystalline semiconductor thin films, such as those used in liquid crystal display devices, face challenges in controlling the positions and diameters of Si crystal grains, leading to variations in electric properties like carrier mobility and threshold voltages, and are costly due to complex mask-making processes.

Innovation Solution

A method involving a transcriptional body with a metal element solution is used to selectively apply and transfer the metal element onto an amorphous semiconductor thin film, acting as crystal nucleuses for controlled crystallization, eliminating the need for complex mask processes and ensuring uniform crystal grain positions and diameters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If energy beams are illuminated onto the amorphous Si thin film on a flat transparent quartz substrate, then the amorphous Si thin film is fused and solidified into a crystalline Si thin film, but the positions and diameters of Si crystal grains cannot be controlled

Engineering Contradiction:
Improvecontrol of crystal grain positions and diametersVSAvoidcomplexity of mask-making processes
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies a solution containing metal elements (such as Ni, Co, or Fe) to the amorphous Si thin film before the crystallization process. This preliminary introduction of metal elements as crystal nucleuses enables controlled crystal grain formation at specific positions with desired diameters, eliminating the need for complex mask-making processes while achieving precise control over crystal grain characteristics

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses metal elements (Ni, Co, or Fe) as intermediary substances that facilitate controlled crystallization. These metal elements act as crystal nucleuses that mediate the transformation from amorphous to crystalline structure, enabling precise control of crystal grain positions and diameters without requiring complex masking procedures

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If a masking material is deposited and photolithography is used to selectively apply metal element solution, then crystal grains can be formed at predetermined positions, but the number of manufacturing processes increases and productivity decreases

Engineering Contradiction:
Improvepositions of crystal grainsVSAvoidproductivity rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent extracts and eliminates the complex mask-making processes (deposition of masking material, photo-resist film application, exposure, development, and etching) from the manufacturing flow. By directly applying the metal element solution to the amorphous Si thin film without these intermediate masking steps, the patent maintains precise control over crystal grain positions while significantly improving productivity and reducing manufacturing costs

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If energy beams are illuminated onto the amorphous Si thin film, then crystalline Si thin film is produced, but variations in electric properties such as carrier mobility and threshold voltages occur due to inconsistent crystal grain characteristics

Engineering Contradiction:
Improveuniformity of electric propertiesVSAvoidconsistency of crystal grain positions and diameters
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces metal elements that selectively promote crystallization at specific locations on the amorphous Si thin film. By controlling where these metal element-containing solutions are applied, the patent creates localized crystal nucleuses that ensure consistent crystal grain positions and diameters across different regions (source regions, channel forming regions, and drain regions), thereby reducing variations in electric properties such as carrier mobility and threshold voltages

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for reliable control of crystal grain positions and diameters, reducing variations in electric properties and manufacturing costs by simplifying the process, resulting in improved performance and productivity of liquid crystal display devices.

Implementation Method 1

transferring the metal element onto the semiconductor thin film; and fusing the semiconductor thin film and crystallizing the semiconductor thin film using the metal element of the solution as crystal producing nucleuses

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

Energy beams are illuminated onto the amorphous semiconductor thin film in order to change amorphous properties to crystal properties, so that a crystalline semiconductor thin film will be formed. Specifically, the amorphous semiconductor thin film is fused by energy beams, is solidified

Methodology Applied
Scientific EffectLaser heating: Laser

Data Source

PatentUS7407848B2Methods of manufacturing semiconductor thin film, electronic device and liquid crystal display device
Publication Date: 2008.08.05 KK TOSHIBA
  • US7407848B2 patent drawing
  • US7407848B2 patent drawing
  • US7407848B2 patent drawing

AI summary

A semiconductor thin film manufacturing method includes: forming a semiconductor thin film on a substrate; forming a transcriptional body containing a metal element on a part thereof; bringing a part of the transcriptional body into contact with the semiconductor thin film, and transferring the metal element onto the semiconductor thin film; and fusing the semiconductor thin film and crystallizing the semiconductor thin film using the metal element of the solution as crystal producing nucleuses.