Semiconductor Pattern Formation via Decomposition Gas Etching

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Solution Overview

Problem

Conventional photolithography processes are limited in forming patterns with fine pitches required for high-integrated semiconductor devices, necessitating a technique to simultaneously create patterns with various widths without increasing the number of photolithography steps.

Innovation Solution

A method involving the formation of a polymer-containing pattern, a porous layer, and a capping layer on a substrate, followed by decomposition and etching to create reduced polymer patterns and voids, which serve as masks for etching, allowing for the formation of patterns with fine pitches exceeding the resolution limits of conventional photolithography.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional photolithography process is used, then manufacturing process is simple, but pattern pitch is limited by resolution

Engineering Contradiction:
Improvepattern pitchVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The manufacturing process is segmented into multiple distinct steps: forming the initial polymer-containing pattern, depositing porous layer, supplying decomposition gas to create reduced pattern, removing porous layer to form spacer pattern, and final etching. This segmentation allows each step to be optimized independently to achieve fine pitch patterns while maintaining process control

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The polymer-containing pattern is formed in advance as a sacrificial structure that guides subsequent pattern formation. The porous layer is deposited beforehand to enable controlled decomposition gas supply. These preliminary actions prepare the system for the precise pattern transformation that follows, allowing the final fine pitch pattern to be achieved through controlled decomposition rather than direct photolithography

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If multiple photolithography processes are used to form patterns with various widths, then pattern width variety is achieved, but number of photolithography steps increases

Engineering Contradiction:
Improvepattern width varietyVSAvoidmanufacturing efficiency
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The decomposition gas supply is applied locally to specific regions where fine pitch patterns are required. The porous layer allows controlled gas penetration only to designated areas, enabling different pattern widths in different regions without requiring separate photolithography processes for each region. This local application of the decomposition process achieves pattern width variety while maintaining manufacturing efficiency

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The method changes the physical and chemical parameters of the pattern formation process by using decomposition gas supply through a porous layer. By controlling decomposition conditions (gas type, temperature, pressure, duration), the same base process can produce patterns of various widths, replacing the need for multiple photolithography processes with parameter-adjusted single process

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of semiconductor device patterns with fine pitches and various widths in a simplified process, reducing the need for additional photolithography steps and improving productivity by lowering costs and complexity.

Implementation Method 1

supplying a decomposition gas to the polymer-containing pattern through the porous layer and decomposing a portion of the polymer-containing pattern

Methodology Applied
Scientific EffectGas permeation through porous material: Permeation

Implementation Method 2

decomposing a portion of the polymer-containing pattern to form a reduced polymer-containing pattern and form a void between the reduced polymer-containing pattern and the porous layer

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Data Source

PatentUS9330931B2Method of manufacturing semiconductor device
Publication Date: 2016.05.03 SAMSUNG ELECTRONICS CO LTD
  • US9330931B2 patent drawing
  • US9330931B2 patent drawing
  • US9330931B2 patent drawing

AI summary

In a method of manufacturing a semiconductor device, which uses a triple patterning process, a porous layer covering sidewalls and an upper surface of a polymer-containing pattern is formed on a layer to be etched. A decomposition gas is supplied to the polymer-containing pattern through the porous layer, and a portion of the polymer-containing pattern is decomposed to form a reduced polymer-containing pattern and form a void between the reduced polymer-containing pattern and the porous layer. A portion of the porous layer is removed to form a porous spacer pattern spaced apart from the reduced polymer-containing pattern. The layer to be etched is etched by using the reduced polymer-containing pattern and the porous spacer pattern as an etch mask.