Non-destructive Semiconductor Depth Profiling via E-beam X-ray Analysis

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current semiconductor industry techniques for material depth-profiling, such as ToF-SIMS and TEM-EDX spectroscopy, are destructive and fail to provide non-destructive z-profiling of materials like fluorine and nitrogen, which are crucial for ensuring device performance and reliability.

Innovation Solution

A computer-based method using electron beams to induce X-ray emissions in semiconductor samples, allowing for non-destructive depth-profiling by projecting electron beams at varying energies to probe different depths, measuring emitted light, and analyzing the data with machine-learning algorithms to determine concentration maps of target materials like fluorine, nitrogen, boron, and gallium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If destructive techniques like ToF-SIMS or TEM-EDX are used for material depth-profiling, then measurement precision of material concentration is improved, but the sample is damaged and cannot be reused

Engineering Contradiction:
Improvematerial concentration measurementVSAvoidsample integrity
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent uses X-ray emissions as an intermediary signal to obtain material concentration information without direct physical contact or destruction of the sample. The e-beam serves as a mediator that excites X-ray emissions from the sample, allowing indirect measurement of material composition at different depths while preserving sample integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces destructive mechanical or chemical analysis methods (ToF-SIMS, TEM-EDX) with a non-destructive electromagnetic radiation-based method. Instead of physically sputtering or sectioning the sample, the invention uses e-beam induced X-ray emissions to probe material composition, substituting mechanical destruction with electromagnetic interaction.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If multiple measurement techniques are used to achieve comprehensive material characterization, then measurement precision is improved, but device complexity increases

Engineering Contradiction:
Improvematerial characterization accuracyVSAvoidmeasurement system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent creates a universal measurement system that can characterize multiple materials (nitrogen, fluorine, boron, gallium, and other group III-V elements) using a single e-beam induced X-ray emission technique. This multi-functional approach replaces the need for multiple specialized instruments (ToF-SIMS, TEM-EDX, etc.) with one versatile platform that handles diverse material analysis through unified physical principles.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables non-destructive, high-resolution depth-profiling of semiconductor materials, providing accurate concentration maps of target materials without damaging the samples, thereby improving device performance and reliability.

Implementation Method 1

Projecting an electron beam (e-beam) on the inspected sample. The e-beam penetrates the sample and induces light-emitting interactions (e.g. X-ray light-emitting interactions) within a respective probed region of the inspected sample

Methodology Applied
Scientific EffectX-ray emission: X-Ray

Data Source

PatentUS20240085351A1Depth-profiling of samples based on x-ray measurements
Publication Date: 2024.03.14 APPL MATERIALS ISRAEL LTD
  • US20240085351A1 patent drawing
  • US20240085351A1 patent drawing
  • US20240085351A1 patent drawing

AI summary

Disclosed herein is a system for non-destructive depth-profiling of samples. The system includes an electron beam source, a light sensor, and processing circuitry. The electron beam source configured to project e-beams on an inspected sample at each of a plurality of landing energies, which induce X-ray emitting interactions within each of a plurality of probed regions in the inspected sample, respectively, whose depth is determined by the landing energy. The light sensor is configured to measure the emitted X-ray light to obtain optical emission data sets pertaining to each of the probed regions, respectively. The processing circuitry is configured to determine a set of structural parameters, characterizing an internal geometry and/or a composition of the inspected sample, based on the measured optical emission data sets and taking into account reference data indicative of an intended design of the inspected sample.