Semiconductor Insulating Regions Suppress Hydrogen Diffusion

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Solution Overview

Problem

Semiconductor devices face instability due to threshold voltage shifts caused by hydrogen diffusion, particularly when a negative voltage is applied for an extended period, leading to the generation of positive charge traps at the interface between the semiconductor region and the insulating layer.

Innovation Solution

The semiconductor device incorporates specific insulating regions with varying compositions of nitrogen and metal oxides, such as Si3N4 and Al2O3, to suppress hydrogen diffusion, thereby stabilizing the device characteristics and preventing threshold voltage shifts.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a simple insulating structure is used, then device complexity is reduced, but threshold voltage instability occurs due to hydrogen diffusion

Engineering Contradiction:
Improvethreshold voltage stabilityVSAvoidinsulating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The insulating portion is divided into multiple insulating regions (first, second, third, and fourth insulating regions) with different compositions and positions. Each region serves a specific function in suppressing hydrogen diffusion from different directions and sources, thereby enhancing threshold voltage stability without using a single complex material system

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different insulating regions are assigned different local compositions: the first insulating region contains nitrogen (e.g., Si3N4) to suppress horizontal hydrogen diffusion, the second insulating region contains metal oxide (e.g., Al2O3) to suppress vertical hydrogen diffusion, and the third insulating region provides additional suppression. This local differentiation optimizes hydrogen barrier performance at each critical interface

Inventive Principle:
Principle #3Local quality

2Reliability

If nitrogen concentration in the first insulating region is increased, then hydrogen diffusion suppression is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvehydrogen diffusion suppressionVSAvoidnitrogen concentration control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent specifies that the nitrogen concentration in the first insulating region should be 5×10^19 to 5×10^21 atoms/cm³, which is lower than conventional uniform nitrogen-rich structures. This localized optimization provides sufficient hydrogen barrier performance while reducing manufacturing complexity and improving process tolerance

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The insulating portion combines multiple materials with different properties: nitrogen-containing material (Si3N4) in the first region for horizontal diffusion suppression, metal oxide (Al2O3) in the second region for vertical diffusion suppression, and additional insulation in the third region. This composite structure achieves superior overall performance while allowing each material to operate within optimal concentration ranges

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these insulating regions with controlled nitrogen and metal oxide compositions effectively reduces hydrogen diffusion coefficients, enhancing the stability and performance of the semiconductor device by minimizing negative threshold voltage shifts.

Implementation Method 1

threshold voltage shifts caused by hydrogen diffusion

Methodology Applied
Scientific EffectHydrogen diffusion: Diffusion

Implementation Method 2

specific insulating regions with varying compositions of nitrogen and metal oxides, such as Si3N4 and Al2O3, to suppress hydrogen diffusion

Methodology Applied
Scientific EffectNitrogen and metal oxide composition control:

Data Source

PatentUS10847649B2Semiconductor device
Publication Date: 2020.11.24 KK TOSHIBA
  • US10847649B2 patent drawing
  • US10847649B2 patent drawing
  • US10847649B2 patent drawing

AI summary

According to one embodiment, a semiconductor device includes first, second, and third semiconductor regions, first, second, and third electrodes, and a first insulating portion. The first semiconductor region includes first and second partial regions. A first direction from the second partial region toward the second semiconductor region crosses a second direction from the second region toward the first partial region. The third semiconductor region is provided between the second partial region and the second semiconductor region in the first direction. The first insulating portion includes a first insulating region provided between the third semiconductor region and the first electrode in the second direction, a second insulating region provided between the first partial region and the first electrode in the first direction, and a third insulating region provided between the first partial region and the first insulating region in the first direction.