Semiconductor Layer Transfer With Low-Temperature Defect Healing

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Solution Overview

Problem

Current methods for creating 3D integrated circuits with superimposed transistors are costly due to the use of SOI substrates and involve thermal processes that degrade lower-level components, and fail to effectively correct surface roughness and defects in the transferred semiconductor layer.

Innovation Solution

A method involving a bulk silicon substrate with ion species implantation, amorphization, and solid-phase recrystallization to transfer a monocrystalline semiconductor layer, using a smoothing layer and selective etching to control thickness and heal defects without degrading the lower-level components, and employing plasma-assisted oxidation and chemical etching to remove surface impurities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If thermal oxidation at 900-1200°C is used to correct surface roughness and control thickness, then surface quality and thickness uniformity are improved, but lower-level components are degraded

Engineering Contradiction:
Improvesurface roughness correctionVSAvoidthermal degradation of lower-level components
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the temperature parameter from conventional 900-1200°C thermal oxidation to low-temperature plasma treatment (below 400°C), achieving surface roughness correction without thermal degradation. This parameter change allows the same functional outcome (surface smoothing) without the harmful thermal effects on lower-level components.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal field (thermal oxidation) with a plasma field (plasma-assisted oxidation). This substitution enables surface treatment through chemical reactions in plasma environment rather than thermal processes, achieving surface quality improvement without the high temperatures that cause component degradation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If heat treatment at temperatures greater than 900°C is used to heal defects, then defect healing is improved, but lower-level components are degraded

Engineering Contradiction:
Improvedefect healingVSAvoidthermal degradation of lower-level components
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the temperature parameter from high-temperature heat treatment (>900°C) to low-temperature plasma treatment (below 400°C). The plasma environment enables defect healing through ion bombardment and chemical reactions rather than thermal diffusion, achieving reliability improvement without thermal damage to lower-level components.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces thermal field-based defect healing with plasma field-based healing. The plasma provides ions, electrons, and reactive species that directly interact with defects in the semiconductor layer, enabling defect annihilation and crystalline structure recovery without the need for high temperatures that would degrade underlying components.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If Smart Cut method with SOI substrate is used for layer transfer, then transfer quality is improved, but manufacturing cost increases

Engineering Contradiction:
Improvelayer transfer qualityVSAvoidmanufacturing cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces expensive SOI substrates with cheaper bulk silicon substrates. The bulk silicon serves as a disposable donor substrate for the transfer process, eliminating the need for costly pre-fabricated SOI wafers while still enabling high-quality layer transfer through the combination of ion implantation and plasma treatment.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the substrate material parameter from SOI (silicon-on-insulator) to bulk silicon. This material parameter change, combined with low-temperature plasma treatment, achieves comparable or superior transfer quality at lower cost by eliminating the expensive SOI substrate requirement while maintaining transfer precision through controlled plasma processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the creation of 3D devices with improved surface roughness and defect healing without thermal degradation of lower-level components, reducing manufacturing costs and enhancing the integrity of the transferred semiconductor layer.

Implementation Method 1

the implantation of ion species into the SOI substrate so as to form a fragilization plane

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 2

recrystallization in solid phase of the amorphous layer to form a transferred monocrystalline semiconductor layer

Methodology Applied
Scientific EffectSolid-phase recrystallization: Crystallisation

Implementation Method 3

plasma-assisted oxidation and chemical etching to remove surface impurities

Methodology Applied
Scientific EffectPlasma-assisted oxidation: Oxidation

Data Source

PatentUS12027421B2Low-temperature method for transfer and healing of a semiconductor layer
Publication Date: 2024.07.02 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • US12027421B2 patent drawing
  • US12027421B2 patent drawing
  • US12027421B2 patent drawing

AI summary

A method for creating a substrate of the semiconductor on insulator type includes steps of a) providing a donor substrate having a monocrystalline support substrate, a smoothing layer and a semiconductor layer, the smoothing layer forming an etch stop layer with respect to the material of the support substrate; a′) implantation of ion species through the semiconductor layer to form a fragilisation plane; b) creating an assembly by placing the donor substrate and a receiver substrate in contact; and c) transferring the semiconductor layer and at least a part of the smoothing layer by detachment along the fragilization plane. The semiconductor layer provided in a) is monocrystalline. The method may further include, before b), amorphization of at least a part of the semiconductor layer to form an amorphous layer; and during or after c), recrystallization in solid phase of the amorphous layer to form a transferred monocrystalline semiconductor layer.