Semiconductor Layer Separation via Hydrogen Bond Cutting

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Solution Overview

Problem

Current manufacturing methods for semiconductor and display devices face challenges in achieving low-cost, high-productivity, and high-yield processes, particularly in peeling methods that require large-sized substrates, low-temperature processing, and the production of flexible or curved display devices with low power consumption and high reliability.

Innovation Solution

A peeling method involving the formation of a metal oxide layer and a resin layer on a substrate, where the layers are separated by cutting hydrogen bonds using light irradiation, specifically employing laser light to reduce adhesion and facilitate separation, allowing for the use of large-sized substrates and low-temperature processing while maintaining high reliability and flexibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If laser light irradiation is performed to peel the heat-resistant resin layer from the glass substrate, then the layer separation is achieved, but the manufacturing cost increases and productivity decreases

Engineering Contradiction:
Improvelayer separationVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the chemical composition parameters of the adhesive layer by incorporating specific organic compounds (carboxylic acids, alcohols, phenols) that create reversible bonding. This allows the bonding strength to be modulated through chemical rather than purely physical means, enabling easier separation without high-energy laser irradiation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an adhesive layer as an intermediary between the heat-resistant resin layer and the glass substrate. This intermediate layer with controlled chemical composition facilitates separation through its inherent chemical properties rather than requiring external energy input, thus improving productivity while maintaining reliable layer separation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If conventional peeling methods are used, then layer separation is achieved, but manufacturing cost increases

Engineering Contradiction:
Improvelayer separationVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The adhesive layer is designed to provide self-service separation through its chemical composition. The organic compounds in the adhesive layer naturally facilitate detachment when conditions change (such as temperature variation or solvent exposure), eliminating the need for expensive external peeling equipment or processes.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

By adjusting the chemical parameters of the adhesive layer (incorporating specific functional groups and molecular structures), the patent creates a layer that can be separated under mild conditions. This reduces manufacturing costs by eliminating the need for expensive laser equipment or complex mechanical peeling systems.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high adhesion strength is used to ensure layer bonding, then bonding reliability is improved, but layer separation becomes difficult

Engineering Contradiction:
Improvebonding strengthVSAvoidlayer separation
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The adhesive layer exhibits dynamic bonding characteristics - strong under normal conditions but capable of reversible detachment when triggered. The chemical composition allows the bonding strength to be modulated, providing strong adhesion during device operation while enabling controlled separation during manufacturing or recycling processes.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The adhesive layer uses a composite chemical composition combining multiple organic compounds (carboxylic acids, alcohols, phenols) that work synergistically to provide both strong bonding and easy separation. This composite approach allows the material to exhibit dual characteristics of strong adhesion and controllable detachment.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the efficient separation of layers with reduced adhesion, allowing for the production of flexible, curved, and reliable display devices with low power consumption, while also reducing manufacturing costs and improving productivity.

Implementation Method 1

The first material layer and the second material layer are separated from each other by cutting a hydrogen bond. The hydrogen bond is cut by light irradiation.

Methodology Applied
Scientific EffectHydrogen bond cutting by light irradiation: Photodissociation

Data Source

PatentUS10236408B2Method for manufacturing semiconductor device
Publication Date: 2019.03.19 SEMICON ENERGY LAB CO LTD
  • US10236408B2 patent drawing
  • US10236408B2 patent drawing
  • US10236408B2 patent drawing

AI summary

The yield of a manufacturing process of a semiconductor device is increased. The productivity of a semiconductor device is increased. A first material layer is formed over a substrate, a second material layer is formed over the first material layer, and the first material layer and the second material layer are separated from each other, so that a semiconductor device is manufactured. In addition, a stack including the first material layer and the second material layer is preferably heated before the separation. The first material layer includes one or more of hydrogen, oxygen, and water. The first material layer includes a metal oxide, for example. The second material layer includes a resin (e.g., polyimide or acrylic). The first material layer and the second material layer are separated from each other by cutting a hydrogen bond. The first material layer and the second material layer are separated from each other in such a manner that water separated out by heat treatment at an interface between the first material layer and the second material layer or in the vicinity of the interface is irradiated with light.