Semiconductor Patterning Process Using Silicon-Containing Film

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Solution Overview

Problem

Current patterning processes face challenges in achieving high overlay accuracy and efficient miniaturization for semiconductor manufacturing, particularly in forming finer patterns with reduced line edge roughness and aberration, due to limitations in light source wavelength and resist material properties.

Innovation Solution

A patterning process involving a positive chemically amplifying photoresist film and a silicon-containing film composition that becomes insoluble with heat or acid, allowing for the formation of a negatively developed pattern and subsequent transfer of the pattern to the substrate using a silicon-containing film as an etching mask, enabling halved pitch patterns with improved resolution and accuracy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If photo lithography with shorter wavelength light sources is used to achieve further miniaturization, then resolution is improved, but manufacturing complexity and cost increase significantly

Engineering Contradiction:
Improvepattern resolutionVSAvoidlithography system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent divides the patterning process into multiple stages: first forming a mandrel pattern, then forming spacer patterns on the sidewalls, and finally transferring the combined pattern to the substrate. This segmentation allows achieving finer effective pitch (half of original pattern pitch) without requiring proportionally more complex lithography equipment, as each stage uses standard lithography processes

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a spacer material as an intermediary element that bridges the gap between the mandrel pattern and the final target pattern. The spacer material (with specific etch selectivity different from both mandrel and substrate) acts as a mediator that enables pattern transfer at half the original pitch through sidewall deposition and etching processes

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If double patterning process with multiple dry-etching steps is used to form finer patterns, then manufacturing precision is improved, but processing time and productivity decrease

Engineering Contradiction:
Improvepattern accuracyVSAvoidprocessing throughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent combines multiple patterning functions into a unified sidewall spacer process flow. Instead of separate double patterning steps with multiple dry-etchings, the method integrates mandrel formation, spacer deposition, and pattern transfer into a coordinated sequence that achieves the same fine pattern resolution with reduced process steps and improved throughput

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If existing patterning methods are used to form half-pitch patterns, then manufacturing precision may be maintained, but line edge roughness increases

Engineering Contradiction:
Improvepattern dimension accuracyVSAvoidline edge roughness
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The spacer material performs multiple functions self-consistently: it forms the sidewall structure, defines the pattern boundary, and serves as the etching mask for transferring the final pattern. This self-service capability of the spacer material ensures consistent line edge definition and reduced roughness, as the same material that forms the pattern boundary is also used to transfer it to the substrate with high fidelity

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables the formation of finer patterns with enhanced overlay accuracy and reduced line edge roughness, addressing the limitations of existing technologies by utilizing a silicon-containing film to efficiently transfer patterns and improve etching selectivity.

Implementation Method 1

forming a silicon-containing film on the substrate to be processed having thereon the negatively developed pattern by applying a silicon-containing film composition comprising a silicon-containing compound capable of becoming insoluble in a solvent by a heat, an acid, or both

Methodology Applied
Scientific EffectHeat-induced insolubilization: Phase Change

Implementation Method 2

forming a silicon-containing film on the substrate to be processed having thereon the negatively developed pattern by applying a silicon-containing film composition comprising a silicon-containing compound capable of becoming insoluble in a solvent by a heat, an acid, or both

Methodology Applied
Scientific EffectAcid-induced insolubilization: Chemical Bonding

Implementation Method 3

forming a photoresist film on a substrate to be processed by using a positive chemically amplifying photoresist film composition which contains an acid generator, followed by subjecting the photoresist film to photo-exposure

Methodology Applied
Scientific EffectPhoto-exposure: Photopolymerisation

Data Source

PatentUS9005883B2Patterning process
Publication Date: 2015.04.14 SHIN ETSU CHEMICAL CO LTD
  • US9005883B2 patent drawing
  • US9005883B2 patent drawing
  • US9005883B2 patent drawing

AI summary

The invention provides a patterning process comprises the steps of: (1) forming a positive chemically amplifying type photoresist film on a substrate to be processed followed by photo-exposure and development thereof by using an organic solvent to obtain a negatively developed pattern, (2) forming a silicon-containing film by applying a silicon-containing film composition comprising a solvent and a silicon-containing compound capable of becoming insoluble in a solvent by a heat, an acid, or both, (3) insolubilizing in a solvent the silicon-containing film in the vicinity of surface of the negatively developed pattern, (4) removing the non-insolubilized part of the silicon-containing film to obtain an insolubilized part as a silicon-containing film pattern, (5) etching the upper part of the silicon-containing film pattern thereby exposing the negatively developed pattern, (6) removing the negatively developed pattern, and (7) transferring the silicon-containing film pattern to the substrate to be processed.