Semiconductor Plating via Nickel Interlayer to Prevent Etch Pits

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Solution Overview

Problem

Conventional semiconductor device manufacturing methods result in performance variations due to etch pits formed on the emitter electrode during the plating process, leading to inconsistent characteristics in the final device.

Innovation Solution

A method involving the formation of a first metal film on the semiconductor substrate, followed by a second metal film with nickel as the main component, which enhances the oxidation rate of the reducing agent in the plating bath, allowing for continuous precipitation of the plated film without the need for etching or zincating treatments, thereby preventing etch pit formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional plating process with etching and zincating treatments is used, then plated film can be formed on emitter electrode, but etch pits are formed causing performance variations

Engineering Contradiction:
Improveconsistency of semiconductor device characteristicsVSAvoidetch pit formation on emitter electrode
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

A nickel-containing metal film is formed on the emitter electrode surface before the plating process to serve as a protective layer that prevents etch pit formation during subsequent plating operations, eliminating the need for etching and zincating treatments

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The nickel-containing metal film acts as an intermediary layer between the emitter electrode and the plating bath, facilitating uniform plated film deposition while protecting the underlying electrode from harmful etching effects

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If etching and zincating treatments are performed before plating, then plated film adhesion is improved, but manufacturing process complexity increases

Engineering Contradiction:
Improveplated film adhesion to emitter electrodeVSAvoidnumber of manufacturing steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The nickel-containing metal film formation step combines the functions of surface preparation and adhesion promotion into a single process step, eliminating the need for separate etching and zincating treatments while ensuring reliable plated film adhesion

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If multiple pre-treatment steps (etching, zincating) are used, then plating quality is improved, but manufacturing time and cost increase

Engineering Contradiction:
Improveplated film uniformityVSAvoidtotal manufacturing cycle time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The nickel-containing metal film is formed in advance as a preparatory step that enables subsequent plating to proceed uniformly without requiring multiple intermediate treatment steps, thereby reducing total manufacturing time while maintaining plating quality

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures consistent semiconductor device characteristics by eliminating etch pits and reducing manufacturing steps, thereby enhancing reliability and reducing costs.

Implementation Method 1

a plated film is formed on the activated surface by a wet plating method in a plating bath that includes a reducing agent that is oxidized during plating

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a reducing agent that is oxidized during plating and that has a rate of oxidation

Methodology Applied
Scientific EffectRedox Reactions: Redox Reactions

Implementation Method 3

forming a plated film on the activated surface by a wet plating method in a plating bath that includes a reducing agent that is oxidized during plating

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Data Source

PatentUS8198104B2Method of manufacturing a semiconductor device
Publication Date: 2012.06.12 FUJI ELECTRIC CO LTD
  • US8198104B2 patent drawing
  • US8198104B2 patent drawing
  • US8198104B2 patent drawing

AI summary

A method of manufacturing a semiconductor device on a semiconductor substrate, includes the steps of forming a first metal film on a front surface of the semiconductor substrate; forming a second metal film on the surface of the first metal film; activating a surface of the second metal film to provide an activated surface; and forming a plated film on the activated surface by a wet plating method in a plating bath that includes a reducing agent that is oxidized during plating and that has a rate of oxidation, wherein the second metal film is a metal film mainly composed of a first substance that enhances the rate of oxidation of the reducing agent in the plating bath. Wet plating is preferably an electroless process.