Semiconductor Spacer Etching to Remove Polymer Residues

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Solution Overview

Problem

The existing photolithography processes struggle to meet the continuously decreasing critical dimensions of semiconductor devices due to the formation of carbon-based polymer residues during etching, which can lead to defects like bumps in subsequent film layers, affecting product yield and productivity.

Innovation Solution

A two-step etching process is employed, where a filling layer is first removed with a high etching rate to expose the spacer, and then with a lower etching rate to specifically remove carbon-based polymers at the boundary of the filling layer and spacer, ensuring the removal of residual polymers and improving the quality of subsequent processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If dry etching is performed using fluorocarbon plasma to etch film layers, then etching capability is improved, but carbon-based polymer residues are formed on the surface of film layers

Engineering Contradiction:
Improveetching rateVSAvoidcarbon-based polymer residues
Core Design Contradiction:
SpeedVSObject-generated harmful factors

Solution Approach 1:

The etching process is divided into two distinct stages: a first etching process that removes a first preset thickness of filling layer, and a second etching process that removes a second preset thickness of filling layer. This segmentation allows each etching process to be optimized independently - the first for high removal rate and the second for polymer residue elimination at boundaries.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different etching rates to different regions and stages of the filling layer removal. The first etching process uses a higher etching rate for bulk material removal, while the second etching process uses a lower etching rate specifically at the boundary regions where polymer residues form, achieving local optimization of both etching efficiency and surface quality.

Inventive Principle:
Principle #3Local quality

2Device complexity

If polymer residues are not removed, then process simplicity is maintained, but subsequent film layers become defective with bumps affecting product yield

Engineering Contradiction:
Improveprocess complexityVSAvoidproduct yield
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent performs preliminary removal of polymer residues during the etching process itself by exposing the spacer and removing carbon-based polymers at the boundary of the filling layer and spacer before subsequent film layer formation. This preliminary action prevents defects in subsequent processes without requiring separate complex cleaning steps.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If a single high etching rate process is used, then productivity is improved, but polymer residues remain at boundaries affecting critical dimension uniformity

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidcritical dimension uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The etching process is divided into two distinct stages: a first etching process that removes a first preset thickness of filling layer, and a second etching process that removes a second preset thickness of filling layer. This segmentation allows each etching process to be optimized independently - the first for high removal rate and the second for polymer residue elimination at boundaries.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different etching rates to different regions and stages of the filling layer removal. The first etching process uses a higher etching rate for bulk material removal, while the second etching process uses a lower etching rate specifically at the boundary regions where polymer residues form, achieving local optimization of both etching efficiency and surface quality.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively eliminates carbon-based polymers, enhancing the stability and quality of semiconductor structures by preventing defects and ensuring even critical dimensions, thereby improving product yield and productivity.

Implementation Method 1

Dry etching is taken as an example, in the dry etching, etching is typically performed using a gas containing fluorocarbon plasma

Methodology Applied
Scientific EffectPlasma etching: Plasma

Implementation Method 2

etching is typically performed using a gas containing fluorocarbon plasma. The adopted gas includes carbon tetrafluoride (CF4), C4F8, C5F8, or C4F6, which may be used as a reaction gas for providing carbon atoms and fluorine atoms

Methodology Applied
Scientific EffectChemical reactions: Chemical Bonding

Implementation Method 3

Etching with such gases typically produces a carbon (C)-based polymer after the etching process

Methodology Applied
Scientific EffectPolymer formation:

Data Source

PatentUS11915933B2Manufacturing method of semiconductor structure
Publication Date: 2024.02.27 CHANGXIN MEMORY TECH INC
  • US11915933B2 patent drawing
  • US11915933B2 patent drawing
  • US11915933B2 patent drawing

AI summary

A manufacturing method of a semiconductor structure is disclosed, which includes: an initial structure is provided; a filling layer covering a spacer is formed on the initial structure; a filling layer with a first preset thickness is removed at a high first etching rate through a first etching process, then a filling layer with a second preset thickness is removed at a low second etching rate through a second etching process, and the partial spacer is exposed; and the filling layer and the spacer are patterned.