Semiconductor Processing Solution for Titanium Residue Removal

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Solution Overview

Problem

Existing processing solutions for semiconductor substrates face challenges in efficiently removing titanium-based residues while maintaining anticorrosion properties, often leading to damage to metal layers due to high concentrations of hydrogen fluoride.

Innovation Solution

A processing solution comprising a compound that releases fluoride ions, an alkali metal or alkaline earth metal ion, and an organic solvent, along with an optional anticorrosive agent, is used to effectively remove titanium-based residues without damaging metal layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a processing solution containing hydrogen fluoride is used to remove dry etching residues, then residue removal properties are improved, but damage to metal layers occurs

Engineering Contradiction:
Improveresidue removal propertiesVSAvoiddamage to metal layers
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the processing solution by replacing hydrogen fluoride with a fluoride ion-releasing compound combined with specific metal ions (alkali metal, alkaline earth metal, or Group III elements). This parameter change maintains effective titanium-based residue removal while reducing harmful effects on metal layers through controlled ion interactions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces intermediary substances (fluoride ion-releasing compounds combined with specific metal ions) that mediate between the need for effective residue removal and the need to protect metal layers. These intermediaries provide the necessary chemical activity for residue removal while their specific ion combinations reduce direct corrosive damage to metal layers

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If conventional processing solutions are used, then residue removal is achieved, but anticorrosion properties are insufficient

Engineering Contradiction:
Improveresidue removalVSAvoidanticorrosion properties
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent creates a composite processing solution by combining fluoride ion-releasing compounds with specific metal ions (alkali metal, alkaline earth metal, or Group III elements) and organic solvents. This composite formulation achieves synergistic effects where the combination provides both effective titanium-based residue removal and improved anticorrosion properties that neither component achieves alone

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution efficiently removes titanium-based residues and enhances anticorrosion properties, reducing damage to metal layers and silicon-based materials, thereby improving semiconductor manufacturing yield and electrical characteristics.

Implementation Method 1

a compound capable of releasing a fluoride ion

Methodology Applied
Scientific EffectFluoride ion release: Chemical Bonding

Implementation Method 2

an organic solvent

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS20250270480A1Processing solution, method for processing semiconductor substrate, and method for manufacturing semiconductor
Publication Date: 2025.08.28 TOKYO OHKA KOGYO CO LTD
  • US20250270480A1 patent drawing
  • US20250270480A1 patent drawing
  • US20250270480A1 patent drawing

AI summary

There are provided a processing solution, including (A) a compound capable of releasing a fluoride ion, (B) at least one selected from the group consisting of an ion of an alkali metal, an ion of an alkaline earth metal, and an ion of an element in Group III of the periodic table, and (C) an organic solvent; a method for processing a semiconductor substrate using the same; and a method for manufacturing a semiconductor using the same.