Sensing Device Cross-Sensitivity Compensation for Ion Detection

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Solution Overview

Problem

Existing sensing devices fail to accurately detect and distinguish between calcium and magnesium ions in water due to cross-sensitivity issues, leading to mineral buildup and residue in appliances, which affects their performance and maintenance.

Innovation Solution

A sensing device comprising a film sensor, a second sensor, and a controller that compensates for cross-sensitivity by using a receptor and a second sensor with distinct sensitivities to unintended analytes, allowing for precise determination of intended analyte concentrations in a fluid medium, incorporating fluorescence-based detection and conductivity measurements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single sensor with a receptor is used to detect analyte concentration, then the device structure is simple, but cross-sensitivity to unintended analytes causes measurement inaccuracy

Engineering Contradiction:
Improvesensor structureVSAvoidanalyte concentration detection
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The sensing system is segmented into multiple independent sensors, each with different receptor specificities. The first sensor uses a receptor with cross-sensitivity to both intended and unintended analytes, while the second sensor uses a receptor with different cross-sensitivity characteristics. This segmentation allows the system to distinguish between analytes by comparing their differential responses.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the sensitivity parameters of the sensors by selecting receptors with different cross-sensitivity characteristics. By choosing receptors with distinct binding affinities and cross-sensitivity profiles, the system creates a parameter difference between sensors that enables mathematical differentiation of analyte concentrations.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If multiple sensors with different sensitivities are used to compensate for cross-sensitivity, then measurement precision improves, but device complexity increases

Engineering Contradiction:
Improveanalyte concentration determinationVSAvoidsensor system configuration
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The system uses feedback from multiple sensor readings to calculate and compensate for cross-sensitivity effects. The controller receives signals from both sensors, applies calibration factors representing known cross-sensitivity characteristics, and iteratively solves the system of equations to determine accurate analyte concentrations.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The sensing system functions as a composite measurement system where two different sensor-receptor combinations work together. Each sensor-receptor pair acts as a component with specific characteristics, and their combined output provides information that neither could provide alone, similar to how composite materials combine properties of individual materials.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate detection and differentiation of calcium and sodium ion concentrations, reducing mineral buildup and improving appliance performance by effectively addressing cross-sensitivity challenges.

Implementation Method 1

The optical sensor detects fluorescence emitted by an intended analyte and an unintended analyte in a fluid medium and captured on a receptor to generate an optical sensor signal

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

The film sensor includes a receptor capturing an intended analyte and an unintended analyte in a fluid medium to generate a film sensor signal

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12135302B2Sensing device compensating for cross-sensitivity to analytes
Publication Date: 2024.11.05 ROBERT BOSCH GMBH
  • US12135302B2 patent drawing
  • US12135302B2 patent drawing
  • US12135302B2 patent drawing

AI summary

A sensing device including film sensor, a second sensor, and a controller. The film sensor includes a receptor capturing an intended analyte and an unintended analyte in a fluid medium to generate a film sensor signal. The receptor has a receptor cross-sensitivity to the unintended analyte. The second sensor contacts the fluid medium including the intended analyte and the unintended analyte to generate a second sensor signal. The second sensor has a second cross-sensitivity to the unintended analyte different than the receptor cross-sensitivity to the unintended analyte. The controller is programmed to determine a concentration of the intended analyte in the fluid medium in response to the film sensor signal, the receptor cross-sensitivity, the second sensor signal, and the second cross-sensitivity.