Vehicle Sensor Repellent Coating for Low-Haze Dirty Water Shedding

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Solution Overview

Problem

Vehicle sensor systems face interference from outdoor environmental elements such as water, dirt, and debris, which can compromise the performance of sensors like cameras, LIDAR, sonar, and radar by causing haze and reducing the effectiveness of repellent coatings used on exterior surfaces.

Innovation Solution

A repellent composition with a high advancing water contact angle and low roll-off angle is applied to the exterior surfaces of vehicle sensors, comprising a cured organic matrix with a high concentration of low surface energy moieties, such as fluorinated groups, and a non-ionic surfactant to effectively repel 'dirty' water, as characterized by the Dirty Water Spray Test, maintaining low haze values.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If repellent coatings are applied to exterior surfaces of vehicle sensors, then water and contaminant repulsion is improved, but haze increases and optical performance deteriorates

Engineering Contradiction:
Improvewater and contaminant repulsionVSAvoidhaze and optical clarity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent applies different surface properties to different regions or aspects of the coating system. The cured organic matrix provides a hydrophobic base layer with high contact angle, while the non-ionic surfactant creates a separate functional layer that reduces surface energy and prevents contaminant adhesion. This layered approach with distinct local qualities allows the coating to repel water and contaminants without significantly increasing haze, as each layer performs its specific function independently.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses a composite coating composition consisting of a cured organic matrix combined with a non-ionic surfactant. The organic matrix provides structural integrity and base hydrophobicity, while the surfactant adds surface energy modification properties. This composite material approach allows the coating to achieve both water repulsion and acceptable optical clarity by combining materials with complementary properties rather than relying on a single substance.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If high concentration of low surface energy moieties is used in the cured organic matrix, then water contact angle increases, but roll-off angle becomes too high reducing repellency effectiveness

Engineering Contradiction:
Improvewater contact angleVSAvoidroll-off angle and contaminant removal
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent carefully controls the concentration of low surface energy moieties in the organic matrix to achieve an optimal balance. By adjusting this parameter, the coating achieves a high enough contact angle for water repulsion while maintaining a low enough roll-off angle for effective contaminant removal. The specific concentration range is optimized to prevent the extremes where either contact angle is too low or roll-off angle is too high.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The non-ionic surfactant acts as an intermediary that mediates between the high contact angle requirement and low roll-off angle requirement. The surfactant molecules position themselves at the coating-water interface, modifying surface properties to enable water to bead up at high angles while still allowing gravity and minor disturbances to cause rolling off at low angles. This intermediary substance resolves the contradiction between contact angle stability and roll-off ease.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If repellent composition is applied to maintain low haze values, then optical performance is improved, but durability against environmental elements deteriorates

Engineering Contradiction:
Improvehaze and optical clarityVSAvoiddurability against water and dirt
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies the repellent composition as a preliminary protective layer before environmental contaminants can adhere to the sensor surface. The coating is applied and cured to form a durable barrier that preemptively prevents water and dirt from bonding to the underlying sensor or lens. This preliminary action maintains optical clarity by stopping contaminant accumulation before it can occur, thereby protecting both optical performance and durability simultaneously.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The cured organic matrix with non-ionic surfactant provides continuous repellent action over time. The hydrophobic surface properties and low surface energy moieties continuously prevent water and contaminant adhesion without degrading or requiring replenishment. This continuous useful action maintains both low haze values and high durability, as the coating actively protects the surface throughout its service life rather than providing temporary or intermittent protection.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a durable and efficient repellent surface that maintains low haze values and ensures the integrity of vehicle sensor systems by effectively repelling water and contaminants, enhancing their performance in harsh outdoor conditions.

Implementation Method 1

a repellent composition disposed on the exterior surface, wherein the repellent composition exhibits an advancing water contact angle from 90° to 125°

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 2

comprising a cured organic matrix with a high concentration of low surface energy moieties, such as fluorinated groups, and a non-ionic surfactant

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP3824325B1Vehicle sensors comprising repellent surface, protective films, repellent coating compositions, and methods
Publication Date: 2025.01.08 3M INNOVATIVE PROPERTIES CO
  • EP3824325B1 patent drawing
  • EP3824325B1 patent drawing
  • EP3824325B1 patent drawing

AI summary

A vehicle sensor system is described comprising an exterior surface; and a repellent composition disposed on the exterior surface, wherein the repellent composition exhibits an increase in haze according to the Dirty Water Spray Test of less than 5, 4, 3, or 2%. In typical embodiments, the repellent composition exhibits an advancing water contact angle from 90° to 125°. In some embodiments, the sensor system comprises a camera, a laser, a LIDAR sensor, a sonar sensor, or a radar sensor. The exterior surface is typically a windshield surface, a protective housing, or a lens surface. In some favored embodiments, the repellent composition exhibits a roll-off angle of no greater than 25, 20, 15, 10 or 5 degrees. Also described is a protective film, a repellent composition, a coating composition, and a method of evaluating repellency