Sensor-Controlled Aqueous Halogen Composition for Bromate Reduction

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Solution Overview

Problem

Existing methods for producing aqueous halogen solutions with multiple halogen species lack control over composition and stability, leading to inefficiencies and unwanted byproducts.

Innovation Solution

A system and method involving controlled production of aqueous halogen solutions with multiple halogen species using sensors, pH adjustment, and halogen stabilizing compounds, along with a control system to optimize desired properties and minimize undesired byproducts.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If aqueous halogen solutions with multiple halogen species are produced without controlled methods, then various halogen components can be present, but the composition and stability cannot be controlled, leading to unwanted byproducts

Engineering Contradiction:
Improvecomposition controlVSAvoidproduction system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The system performs preliminary actions by pre-adjusting the pH of the hypochlorite solution before introducing halide ions. This preliminary pH adjustment ensures that the subsequent reactions proceed in a controlled manner, producing the desired mixed halogen species while minimizing unwanted byproducts like bromate ions.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention utilizes parameter changes by systematically varying pH levels and halide ion concentrations during the production process. By controlling these parameters in sequence, the system achieves precise composition control of multiple halogen species while maintaining stability and reducing harmful byproducts.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If aqueous halogen solutions with multiple halogen species are produced, then biocidal properties and halogen stability can be improved, but corrosivity and unwanted byproduct formation increase

Engineering Contradiction:
Improvebiocidal efficacyVSAvoidbromate ion formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The system controls the formation of halogen species by precisely adjusting pH parameters and halide ion concentrations. This parameter control enables the production of solutions with enhanced biocidal efficacy while minimizing the formation of harmful byproducts such as bromate ions, thus resolving the contradiction between reliability and harmful factors.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If sensors and control systems are added to monitor and control the production process, then composition precision and stability are improved, but system complexity and cost increase

Engineering Contradiction:
Improvehalogen composition precisionVSAvoidcontrol system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention incorporates feedback mechanisms through sensors that continuously monitor pH levels, halogen species concentrations, and other critical parameters. This real-time feedback enables the control system to automatically adjust production parameters, achieving precise composition control while managing system complexity through automated closed-loop control.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The control system is designed to automatically monitor and adjust production parameters without requiring constant manual intervention. The sensors and control mechanisms serve themselves by automatically detecting deviations and making corrections, thereby improving precision while keeping the operational complexity manageable.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of aqueous halogen solutions with precise composition and stability, ensuring optimal biocidal properties and reducing corrosivity, while minimizing bromate ion formation.

Implementation Method 1

The system further comprises a control system having a multitude of sensors capable of monitoring chemical and physical properties of aqueous solutions

Methodology Applied
Scientific EffectSensing:

Implementation Method 2

modifying aqueous solutions of hypochlorite ions through the sequential addition of pH adjusting chemicals, halide ions, and halogen stabilizing compounds

Methodology Applied
Scientific EffectpH adjustment:

Implementation Method 3

provide at least one halogen stabilizing compound

Methodology Applied
Scientific EffectComplexation:

Data Source

PatentUS12403444B2Controlled production of aqueous halogen solutions with varying compositions
Publication Date: 2025.09.02 DE NORA HOLDINGS US INC
  • US12403444B2 patent drawing
  • US12403444B2 patent drawing
  • US12403444B2 patent drawing

AI summary

Methods and systems for the controlled production of aqueous halogen solutions with varying compositions are disclosed. According to an embodiment, aqueous solutions of hypochlorite ions are modified through the sequential addition of pH adjusting chemicals, non-chloride halide ions, and halogen stabilizing compounds. Sensors, for measuring physical and chemical properties of the solutions as they change due to the impact of the various chemical reactions, are linked to a control system which, in turn, can control the input of one or more chemicals. The control system facilitates the production of a solution with desired characteristics in terms of pH, specific halogen composition, degree of halogen stabilization, and limiting the production of undesired by products such as bromate ions.