Water Analysis Sensor Electrode Capillary Bubble Removal

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Solution Overview

Problem

Small-diameter water analysis sensor electrodes face issues with gas bubbles becoming stuck between the sensor electrode membrane and the measuring electrode due to surface tension, leading to electrical connection interruptions, which are difficult to resolve without visual inspection.

Innovation Solution

A continuous open capillary channel on the inner wall of the sensor electrode housing, combined with a denser rod element that rests against the inner wall, utilizes capillary action and gravity to flush out gas bubbles, preventing them from becoming stuck, while ensuring chemical inertness to maintain measurement quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If a small-diameter sensor electrode housing is used, then the sensor electrode becomes more compact and easier to handle, but gas bubbles become stuck between the membrane and measuring electrode due to surface tension effects

Engineering Contradiction:
Improvesensor electrode housing volumeVSAvoidelectrical connection reliability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent introduces a capillary channel that segments the internal space of the sensor electrode housing, creating a dedicated pathway for electrolyte solution to reach and flush trapped gas bubbles. This segmentation allows the system to maintain compact dimensions while ensuring reliable electrical connections by preventing gas bubble accumulation in critical areas.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The capillary channel acts as an intermediary structure that facilitates the movement of electrolyte solution to trapped gas bubbles. Through capillary action, the channel mediates the interaction between the electrolyte solution and gas bubbles, enabling the flushing process that removes trapped bubbles and restores electrical connectivity without requiring manual intervention.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If the sensor electrode housing is turned upside down during transport, then the gas bubble migrates against gravity into the area between the membrane and measuring electrode, but this positioning cannot be visually detected

Engineering Contradiction:
Improvetransport flexibilityVSAvoidgas bubble detection difficulty
Core Design Contradiction:
Ease of operationVSDifficulty of detecting and measuring

Solution Approach 1:

The capillary channel enables the sensor electrode to self-correct the gas bubble positioning issue automatically. When the electrode is turned upside down during transport, the capillary channel self-activates through capillary action to flush the trapped gas bubble out of the critical area, eliminating the need for visual inspection or manual tapping to detect and resolve the problem.

Inventive Principle:
Principle #25Self-service

3Reliability

If a rod element with higher density than electrolyte solution is inserted, then the rod element rests on the bottom and effectively flushes gas bubbles, but this adds structural complexity

Engineering Contradiction:
Improvegas bubble flushing effectivenessVSAvoidinternal structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the gas bubble removal function from manual operations (tapping or visual inspection) and implements it through a passive structural element - the rod element. By taking out the active intervention requirement and replacing it with a passive density-based positioning system, the patent simplifies the overall operation while maintaining effective gas bubble flushing.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively prevents gas bubbles from becoming stuck, ensuring reliable electrical connections and maintaining measurement quality without visual checks, by using capillary action and adhesive forces to flush out bubbles, thus addressing the issue of stuck gas bubbles in small-diameter sensor electrodes.

Implementation Method 1

In the area of the capillary groove, the effect of surface tension is weakened to such an extent that gravity is usually sufficient to allow the electrolyte solution to flow under a gas bubble below. If a gas bubble is present in the lower area of the sensor electrode, i.e. in the area between the sensor electrode membrane and the measuring electrode, the gas bubble will be undermined by the electrolyte solution in the sensor electrode housing as a result of the capillary action in the capillary channel.

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

Inside the sensor electrode housing, the rod element can rest solely by adhesion to the inner wall.

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

The density of the material used for the rod element is greater than the density of the electrolyte solution, so that the rod element rests on the bottom of the sensor electrode housing and the gas bubble can thus be effectively flushed with the electrolyte solution.

Methodology Applied
Scientific EffectGravity: Gravitation

Data Source

PatentEP2410321B1Water analysis sensor electrode
Publication Date: 2017.03.08 HACH LANGE HACH LANGE
  • EP2410321B1 patent drawing
  • EP2410321B1 patent drawing
  • EP2410321B1 patent drawing

AI summary

The sensor electrode (10) has a closed sensor electrode housing (12) with an electrolyte solution (18), a measuring electrode (14) arranged in the electrolyte solution and a gas bubble (20) enclosed in the sensor electrode housing. A rigid rod element (22) of circular cross section is inserted into the interior of the sensor electrode housing, such that a continuous open capillary channel extends over the axial length of the sensor electrode housing on the inner wall (24) between the rod element and the inner wall.