Sensor Manufacturing Using Spontaneous Transition Layer

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Solution Overview

Problem

Existing gas sensors using metal oxide nanoparticles face challenges in maintaining gas response while stabilizing nanoparticles on device electrodes, as high-temperature heat used to remove bonding agents can lead to contamination and unexpected characteristics.

Innovation Solution

A method of manufacturing a sensor involving the formation of a sensor layer by coating nanoparticle layers with cobalt oxide, forming a spontaneous transition layer with cobalt hydroxide using deionized water, and annealing at temperatures between 300° C to 700° C to enhance adhesive force and gas response.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If high-temperature heat is applied to remove bonding agent, then bonding agent is removed, but nanoparticle contamination occurs and unexpected characteristics arise

Engineering Contradiction:
Improvebonding agent removalVSAvoidnanoparticle purity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent extracts and removes the organic bonding agent (alpha-terpineol) from the nanoparticle mixture through solvent extraction using a non-aqueous solvent, separating the bonding agent from the metal oxide nanoparticles without requiring high-temperature heat treatment that would cause contamination

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces a non-aqueous solvent as an intermediary substance to dissolve and remove the organic bonding agent, acting as a mediator between the nanoparticle layer and the bonding agent removal process, avoiding direct high-temperature thermal processing

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If nanoparticles are immobilized using organic bonding agent, then nanoparticles are fixed on electrode, but gas response is compromised

Engineering Contradiction:
Improvenanoparticle fixationVSAvoidgas response
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent removes the organic bonding agent from the nanoparticle composition through solvent extraction, eliminating the substance that compromises gas response while maintaining nanoparticle fixation through alternative means

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a soluble organic compound as a temporary bonding agent that can be easily removed by solvent extraction, allowing the nanoparticles to be fixed during processing and then released to maintain their gas sensing capability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of manufacture

If high-temperature heat is applied to process sensor layer, then sensor layer is formed, but space between sensor materials and device is affected

Engineering Contradiction:
Improvesensor layer formationVSAvoidspace between sensor materials and device
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent replaces high-temperature thermal processing with a chemical solvent extraction method to remove bonding agents, substituting thermal mechanics with chemical processes to achieve sensor layer formation without affecting the spacing between sensor materials and device components

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a sensor layer with improved adhesive force and gas response, achieving stability and performance comparable to or exceeding that of typical sensor layers, with a response of 0.6 to 0.7 and long-term stability of 0.5 to 0.6.

Implementation Method 1

providing deionized water on the nanoparticle layer to form a spontaneous transition layer which includes cobalt hydroxide

Methodology Applied
Scientific EffectSpontaneous transition:

Implementation Method 2

annealing the spontaneous transition layer at a temperature of 300° C. to 700° C. to form the sensor layer

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS12209988B2Sensor and method of manufacturing the same
Publication Date: 2025.01.28 ELECTRONICS & TELECOMM RES INST
  • US12209988B2 patent drawing
  • US12209988B2 patent drawing
  • US12209988B2 patent drawing

AI summary

Disclosed is a sensor and a method of manufacturing the same. The method includes forming a plurality of electrodes on a substrate and forming a sensor layer on the substrate between the plurality of electrodes. The forming of the sensor layer includes coating a nanoparticle layer, providing deionized water on the nanoparticle layer to form a spontaneous transition layer, and annealing the spontaneous transition layer to form the sensor layer.