Composite Separator Coating for High-Voltage Dielectric Stability

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Solution Overview

Problem

Conventional polyolefin-based separators for electrochemical devices exhibit low heat resistance and are prone to short-circuits due to shrinkage or melting at high temperatures, while thin-film separators face challenges in maintaining insulation properties and mechanical strength.

Innovation Solution

A separator for electrochemical devices is developed, comprising a polymer porous support coated with an inorganic composite porous layer. This layer includes a binder polymer with a glass transition temperature of 180°C or higher and an inorganic filler, providing enhanced heat resistance and mechanical strength, along with a dielectric breakdown voltage of 2 kV or more.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polyolefin-based separator is used, then the separator provides good ion conductivity and mechanical properties, but it shows low heat resistance and shrinks or melts at high temperature causing short-circuits

Engineering Contradiction:
Improveion conductivityVSAvoidheat resistance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent applies composite materials by combining polyolefin base material with inorganic particles (such as alumina, silica) and binder polymers (such as polyacrylic acid, carboxymethyl cellulose). This composite structure maintains the ion conductivity of the polyolefin while the inorganic particles provide high-temperature stability and prevent shrinkage or melting at elevated temperatures, thereby resolving the contradiction between ion conductivity and heat resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of the separator by controlling the particle size distribution (D10, D50, D90 values), inorganic particle content (30-200 parts by weight per 100 parts binder polymer), and binder polymer composition. These parameter changes enhance the heat resistance while maintaining porosity (30-80%) for ion conductivity, allowing the separator to withstand temperatures up to 200°C without structural collapse.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If the separator is thinned to increase energy density, then the energy density improves, but the insulation property and mechanical strength degrade

Engineering Contradiction:
Improveenergy densityVSAvoidmechanical strength
Core Design Contradiction:
Use of energy by moving objectVSStrength

Solution Approach 1:

The patent utilizes porous inorganic particles with controlled pore structures to create a lightweight, thin separator structure. The porous network provides mechanical reinforcement through the inorganic particle framework while maintaining high porosity (30-80%) for ion transport. This allows the separator to be thinner (5-20 μm) for higher energy density while the interconnected porous structure of inorganic particles provides sufficient mechanical strength and insulation properties.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The composite structure of inorganic particles embedded in a binder polymer matrix provides exceptional mechanical strength for a thin separator. The inorganic particles form a rigid scaffold that prevents deformation and maintains insulation, while the binder polymer holds the particles together. This composite approach enables the separator to achieve both thinness (for high energy density) and mechanical robustness (for safety).

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed separator effectively reduces the short-circuit generation ratio and maintains excellent insulation properties, even at high temperatures, thereby enhancing the safety and performance of electrochemical devices.

Implementation Method 1

the binder polymer includes an amorphous polymer having a glass transition temperature (Tg) of 180° C. or higher

Methodology Applied
Scientific EffectGlass transition temperature:

Implementation Method 2

the separator shows a dielectric breakdown voltage of 2 kV or more

Methodology Applied
Scientific EffectDielectric breakdown: Dielectric

Data Source

PatentUS20250112330A1Separator for Electrochemical Device and Electrochemical Device Including the Same
Publication Date: 2025.04.03 LG CHEM LTD
  • US20250112330A1 patent drawing

AI summary

A separator for an electrochemical device; includes a polymer porous support and an inorganic composite porous layer formed on at least one surface of the porous support. The inorganic composite porous layer includes a binder polymer and an inorganic filler, the binder polymer includes an amorphous polymer having a glass transition temperature (Tg) of 180° C. or higher, the content of the inorganic filler is 30-200 parts by weight based on 100 parts by weight of the binder polymer, and the separator shows a dielectric breakdown voltage of 2 kV or more. The separator for an electrochemical device provides an electrochemical device with improved voltage resistance characteristics to realize a high dielectric breakdown voltage, and can provide a reduced short-circuit generation ratio (defect rate in a Hi-Pot test) even under a high voltage condition. An electrochemical device including the separator is also provided.