Thermochromic Separator Coating for Early Battery Heat Warning
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Solution Overview
Problem
Secondary batteries face reliability issues due to poor thermal resistance of current separators, leading to thermal shrinkage and increased safety risks such as short circuits and explosions.
Innovation Solution
A separator with a thermochromic coating containing materials like azobenzene, stearate, higher aliphatic alcohol, and inorganic metal salts that change color with temperature changes, allowing early detection of thermal runaway and reducing the risk of explosion.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a conventional separator is used, then the battery structure is simple, but the thermal resistance is poor leading to thermal shrinkage and safety risks
Solution Approach 1:
The patent applies composite materials by combining a base separator material with thermochromic materials to create a multi-functional separator. The thermochromic coating layer is formed on the base separator, creating a composite structure that provides both separation function and thermal detection capability. This resolves the contradiction by improving thermal resistance through the composite structure while maintaining relatively simple manufacturing processes.
Solution Approach 2:
The patent applies local quality by adding thermochromic materials specifically to the separator surface through coating, rather than modifying the entire separator bulk. The thermochromic coating layer is localized on the separator surface, providing thermal detection functionality where it is most needed for safety monitoring, while the base separator maintains its original separation function. This resolves the contradiction by improving thermal resistance locally without significantly increasing overall device complexity.
2Measurement precision
If no thermal detection mechanism is added, then the device complexity is low, but the ability to detect thermal runaway early is insufficient
Solution Approach 1:
The patent applies color changes by utilizing thermochromic materials that change color in response to temperature changes. The thermochromic coating on the separator transitions from one color state to another when thermal runaway occurs or is approaching, providing visual indication of thermal status. This resolves the contradiction by enabling precise thermal runaway detection through color change without requiring complex electronic sensing systems.
Solution Approach 2:
The patent applies self-service by enabling the separator to perform its own thermal detection function through the thermochromic coating. The separator itself becomes the detection element, eliminating the need for separate external sensors or monitoring systems. The thermochromic material automatically responds to temperature changes, providing self-diagnostic capability. This resolves the contradiction by achieving precise thermal detection while minimizing device complexity.
3Reliability
If the separator thickness is increased to improve thermal resistance, then the thermal safety improves, but the battery energy density decreases
Solution Approach 1:
The patent applies composite materials by creating a thin thermochromic coating on the separator surface, adding thermal detection and resistance functionality without significantly increasing overall separator thickness. The coating layer provides enhanced thermal safety properties while occupying minimal volume, thus preserving battery energy density. This resolves the contradiction by improving thermal safety through surface-level composite structure rather than bulk thickness increase.
Solution Approach 2:
The patent applies local quality by concentrating the thermal safety enhancement in a thin surface coating rather than increasing the bulk separator thickness. The thermochromic coating provides localized thermal resistance and detection capability at the separator surface, maintaining the overall thin profile of the separator. This resolves the contradiction by improving thermal safety locally without compromising the quantity of active materials and thus energy density.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The thermochromic coating enables timely detection of thermal runaway, improving safety by reducing the risk of explosions and enhancing the reliability and cycle performance of secondary batteries.
Implementation Method 1
the coating includes a thermochromic material... A color of the thermochromic material may change with a change of an internal temperature of a battery
Data Source
AI summary
The present application provides a separator, a secondary battery including a separator, and a power consuming apparatus. The separator includes a first base film and a coating. The coating is located on a surface of the first base film, and the coating includes a thermochromic material.

