Fuel Cell Separator Plate Flake Graphite Aspect Ratio

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Solution Overview

Problem

Fuel cells using flake graphite in separator plates face challenges with anisotropic conductivity, leading to unbalanced in-plane and thru-plane thermal conductivities, which affects cell stack assembly, acid condensation zone temperature, and fuel cell lifetime.

Innovation Solution

A fuel cell separator plate is designed with flake graphite particles having a reduced aspect ratio (length to thickness ratio of less than 10, typically between 5.0 and 7.5) and a polymer, optimizing flake orientation to enhance isotropic thermal conductivity and reduce in-plane heat flow.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If flake graphite is used in fuel cell separator plates, then corrosion resistance and packing density are improved, but thermal conductivity becomes anisotropic with lower thru-plane conductivity

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidthru-plane thermal conductivity
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent applies parameter changes by modifying the aspect ratio of flake graphite particles from the conventional high aspect ratio (typically 20:1 or higher) to a reduced aspect ratio of less than 10:1 (specifically between 5.0 and 7.5). This parameter change in particle geometry transforms the thermal conductivity characteristics from highly anisotropic to more isotropic, improving thru-plane thermal conductivity while maintaining the corrosion resistance benefits of flake graphite in phosphoric acid fuel cells.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If flake graphite is used in fuel cell separator plates, then packing density increases and fluoropolymer requirements decrease, but in-plane conductivity becomes higher than desired

Engineering Contradiction:
Improvefluoropolymer requirementsVSAvoidin-plane thermal conductivity
Core Design Contradiction:
Quantity of substanceVSTemperature

Solution Approach 1:

The patent applies parameter changes by modifying the aspect ratio of flake graphite particles from the conventional high aspect ratio (typically 20:1 or higher) to a reduced aspect ratio of less than 10:1 (specifically between 5.0 and 7.5). This parameter change in particle geometry transforms the thermal conductivity characteristics from highly anisotropic to more isotropic, improving thru-plane thermal conductivity while maintaining the corrosion resistance benefits of flake graphite in phosphoric acid fuel cells.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional high aspect ratio flake graphite is used, then manufacturing efficiency is maintained, but thermal conductivity anisotropy affects cell stack assembly and acid condensation zone temperature

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidacid condensation zone temperature
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The patent applies parameter changes by modifying the aspect ratio of flake graphite particles from the conventional high aspect ratio (typically 20:1 or higher) to a reduced aspect ratio of less than 10:1 (specifically between 5.0 and 7.5). This parameter change in particle geometry transforms the thermal conductivity characteristics from highly anisotropic to more isotropic, improving thru-plane thermal conductivity while maintaining the corrosion resistance benefits of flake graphite in phosphoric acid fuel cells.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration decreases in-plane thermal conductivity, prolongs fuel cell life by managing acid evaporation rates and provides design flexibility with more balanced thermal performance.

Implementation Method 1

optimize the thermal conductivity of a fuel cell component

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

decreases in-plane thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentEP3111496B1Fuel cell component including flake graphite
Publication Date: 2021.12.08 DOOSAN FUEL CELL AMERICA INC
  • EP3111496B1 patent drawingFigure 1~2
  • EP3111496B1 patent drawingFigure 3

AI summary

A fuel cell separator plate includes flake graphite particles having a length along a planar direction and a thickness along a generally perpendicular direction. The flake graphite has an aspect ratio of length to thickness that is less than ten.