Sepiolite Clay Polymer Well Treatment Fluid High Temperature Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Well treatment fluids experience deterioration in viscosity and yield point at elevated temperatures above 300° F, leading to premature settling of solid materials, which affects the effectiveness of drilling, cementing, and fracturing operations in oil and gas wells.

Innovation Solution

A well treatment fluid comprising an aqueous base fluid, sepiolite clay, and a polymer component such as acryloylmorpholine or polyvinylpyrrolidone polymers, which synergistically maintains rheological properties and temperature stability up to 325° F, enhancing the fluid's ability to suspend solids and perform well treatment operations effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional well treatment fluids are used at elevated temperatures above 300° F, then the fluid can reach high-temperature environments, but the viscosity and yield point deteriorate causing solid materials to settle prematurely

Engineering Contradiction:
Improvetemperature stabilityVSAvoidrheological properties
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent combines multiple polymer components (acrylamide-based polymer and polyacrylate-based polymer) with sepiolite clay to create a composite fluid system. This composite approach allows the fluid to maintain rheological properties at high temperatures by leveraging the synergistic effects of different materials, each contributing specific temperature-resistant characteristics that prevent viscosity deterioration and solid material settling.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the well treatment fluid by incorporating specific polymers and clays in controlled amounts. By adjusting the concentration and type of polymers (acrylamide-based and polyacrylate-based) and sepiolite clay, the fluid's rheological parameters are optimized to remain stable at elevated temperatures above 300° F, preventing the deterioration that would otherwise cause solid material settling.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If viscosifiers and suspending agents are added to maintain rheological properties, then the fluid can suspend solid materials, but the temperature above 300° F causes these additives to break down

Engineering Contradiction:
Improvesuspension capabilityVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent creates a composite suspension system using sepiolite clay combined with acrylamide-based and polyacrylate-based polymers. This composite structure provides thermal stability up to 300° F and above, allowing the suspension capability to be maintained at high temperatures where conventional single-component viscosifiers would break down. The synergistic interaction between the clay and polymer components prevents additive degradation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The sepiolite clay acts as an intermediary substance that stabilizes the polymer components at high temperatures. The clay particles interact with the polymers to form a stable network structure that prevents thermal degradation of the suspending agents, thereby maintaining suspension capability in high-temperature environments where conventional additives would fail.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If high viscosity is maintained to suspend solids, then solid materials remain suspended, but the fluid loses effectiveness at high temperatures due to rheological breakdown

Engineering Contradiction:
Improvesolid suspensionVSAvoidrheological deterioration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs a composite formulation of acrylamide-based polymers, polyacrylate-based polymers, and sepiolite clay that maintains high viscosity and yield point at elevated temperatures. This composite system prevents rheological deterioration by creating a thermally stable network structure that continues to effectively suspend solid materials even in high-temperature environments above 300° F, eliminating the trade-off between viscosity maintenance and thermal stability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The synergy between sepiolite clay and polymer components significantly improves the temperature stability and rheological properties of well treatment fluids, ensuring effective suspension of solids and performance in high-temperature environments, thereby extending the operational range of well treatment fluids beyond 300° F.

Implementation Method 1

The synergy between sepiolite and the polymer component(s) significantly improves the temperature stability and rheological properties of well treatment fluids

Methodology Applied
Scientific EffectRheological modification:

Implementation Method 2

maintains rheological properties and temperature stability up to 325° F

Methodology Applied
Scientific EffectThermal stabilization:

Implementation Method 3

enhancing the fluid's ability to suspend solids

Methodology Applied
Scientific EffectSuspension: Suspension

Data Source

PatentUS11566172B2Downhole high temperature rheology control
Publication Date: 2023.01.31 HALLIBURTON ENERGY SERVICES INC
  • US11566172B2 patent drawing

AI summary

A method of treating a well comprising introducing a well treatment fluid into the well, and a well treatment fluid, are provided. The well treatment fluid comprises an aqueous base fluid, sepiolite clay, and a polymer component selected from the group of an acryloylmorpholine polymer, a polyvinylpyrrolidone polymer, and mixtures thereof. In one embodiment, for example, the method is a method of drilling a well. In this embodiment, the well treatment fluid is a drilling fluid.