Sequential Biological Target Detection via Fluorescence Bleaching

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Solution Overview

Problem

Current methods for analyzing biological samples can only detect a limited number of targets simultaneously, requiring multiple samples and limiting the ability to determine the presence, absence, concentration, and spatial distribution of multiple biological targets.

Innovation Solution

The method involves using probes with binders coupled to enzymes and fluorescent signal generators, where the bound probes are reacted with enzyme substrates and an oxidizing agent, allowing for iterative detection and analysis of multiple targets in a single sample by modifying and reusing the signal generators.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If multiple targets are detected simultaneously using fluorescence-based detection systems, then the number of detectable targets increases, but the complexity of the detection system and sample preparation requirements increase

Engineering Contradiction:
Improvenumber of detectable targetsVSAvoiddetection system complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The detection process is segmented into sequential steps where one target is detected, the signal is destroyed, and then the next target is detected. This segmentation allows multiple targets to be detected using a single detection channel without requiring complex multi-channel systems, thus reducing device complexity while maintaining the ability to detect multiple targets.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The method employs periodic action by cycling through detection-destroy-reaction sequences for each target. The fluorescent signal generator is periodically activated and then destroyed, allowing the detection system to focus on one target at a time in a rhythmic sequence, enabling multiple target detection without simultaneous signal interference.

Inventive Principle:
Principle #19Periodic action

2Measurement precision

If multiple biological samples are used to analyze different targets, then the ability to determine relative characteristics improves, but the sample availability and analysis efficiency deteriorate

Engineering Contradiction:
Improverelative characteristics analysisVSAvoidsample analysis efficiency
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

A single biological sample is made universal for analyzing multiple different targets through sequential detection. The same sample serves multiple functions by allowing repeated detection cycles with different probes, eliminating the need to use multiple separate samples and thereby improving analysis efficiency while maintaining measurement precision.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The fluorescent signal generator is intentionally destroyed after each detection cycle to prevent signal interference in subsequent detections. This controlled discarding of the signal generator allows the sample to be reused for the next target detection, improving productivity while maintaining the ability to analyze relative characteristics through sequential measurements.

Inventive Principle:
Principle #34Discarding and recovering

3Productivity

If fluorescent signal generators are reused for multiple detections, then sample utilization improves, but signal interference between detections increases

Engineering Contradiction:
Improvesample utilizationVSAvoidsignal interference
Core Design Contradiction:
ProductivityVSDifficulty of detecting and measuring

Solution Approach 1:

The potential harmful effect of signal persistence is converted into a benefit by intentionally destroying the fluorescent signal generator after each detection. This controlled destruction eliminates signal interference between detections, allowing the same sample to be utilized for multiple targets without contamination from previous signals, thus improving both productivity and measurement accuracy.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the detection of multiple targets in a single biological sample with minimal sample disruption, providing spatial information and allowing for multiple analyses without stripping probes, thus overcoming the limitations of existing techniques.

Implementation Method 1

applying to the sample a solution containing an oxidizing agent that substantially inactivates both the fluorescent signal generator and the enzyme

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

reacting the bound probe with an enzyme substrate coupled to a fluorescent signal generator

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Implementation Method 3

enzyme substrate coupled to a fluorescent signal generator

Methodology Applied
Scientific EffectChemiluminescence: Chemiluminescence

Implementation Method 4

binding at least one probe having a binder coupled to an enzyme to one or more target present in the sample

Methodology Applied
Scientific EffectMolecular recognition:

Data Source

PatentEP2082238B1Sequential analysis of biological samples with intermediate bleaching of fluorescence detector
Publication Date: 2012.01.11 GENERAL ELECTRIC CO
  • EP2082238B1 patent drawingFigure 1
  • EP2082238B1 patent drawingFigure 2
  • EP2082238B1 patent drawingFigure 3

AI summary

Methods for probing multiple targets in a biological sample are provided. The methods include the steps of providing a sample containing multiple targets, binding at least one probe having a binder coupled to an enzyme to one or more target present in the sample, and reacting the bound probe with an enzyme substrate coupled to a fluorescent signal generator. The methods include the steps of observing a signal from the fluorescent signal generator and applying to the sample a solution containing an oxidizing agent that substantially inactivates both the fluorescent signal generator and the enzyme. The methods further include the steps of binding at least one probe having a binder coupled to an enzyme to one or more target present in the sample of step, reacting the bound probe with an enzyme substrate coupled to a fluorescent signal generator; and observing a signal from the fluorescent signal generator. The methods disclosed herein also provide for multiple iterations of binding, observing, and oxidizing for deriving information about multiple targets in a single sample. An associated kit is also provided.