Shape-Changing Polymers for Reversible Lost Circulation Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional lost circulation materials (LCMs) used in subterranean operations can only change shape once and do not revert back to their original state, limiting their effectiveness in various drilling fluids and well conditions, necessitating the need for novel materials that can change shape multiple times and maintain their structure in different temperature ranges.

Innovation Solution

The development of shape-changing polymer structures, specifically polymeric units that can elongate or contract reversibly with temperature changes, allowing them to be folded or rolled into compact forms for deployment and expand or contract in response to downhole temperatures, enhancing their functionality in drilling fluids and wellbore applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional lost circulation materials are used, then they can control fluid loss in subterranean zones, but they can only change shape once and do not revert back to their original state, limiting their effectiveness

Engineering Contradiction:
Improveeffectiveness of lost circulation controlVSAvoidreversibility of shape change
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by utilizing temperature as a triggering parameter to induce reversible shape changes in the polymer structure. The polymer transitions between contracted and extended states based on temperature variations, enabling multiple cycles of shape change and recovery, thereby resolving the contradiction between reliability and adaptability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces dynamic behavior to the lost circulation material through reversible shape changes. The polymer structure can dynamically adjust its configuration in response to temperature changes, transitioning from a contracted state during deployment to an extended state during recovery, and back again, providing continuous adaptability and enhanced reliability.

Inventive Principle:
Principle #15Dynamics

2Adaptability or versatility

If polymers are used to change shape in response to fluid properties, then they can adapt to different treatment fluids, but the shape changing is often triggered by a change in fluid properties, requiring different polymer materials for different treatment fluids

Engineering Contradiction:
Improvecompatibility with different treatment fluidsVSAvoidvariety of polymer materials required
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies universality by designing a polymer structure that responds to temperature changes rather than fluid composition changes. This universal temperature-triggered mechanism allows the same polymer material to function effectively across different treatment fluid types, eliminating the need for multiple specialized polymer materials and reducing device complexity while maintaining adaptability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Shape

If the substrate structure dissolves in the fluid, then the polymer can change shape, but the polymer is not able to revert back to its original state

Engineering Contradiction:
Improveshape change capabilityVSAvoidpermanence of shape change
Core Design Contradiction:
ShapeVSStability of the object's composition

Solution Approach 1:

The invention uses parameter changes by triggering shape changes through reversible temperature-induced conformational transitions rather than substrate dissolution. The polymer structure maintains its integrity while undergoing reversible shape changes, allowing it to return to its original state after deformation, thus resolving the contradiction between shape change capability and compositional stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These shape-changing polymers can be used in a variety of drilling fluids, maintain their structure, and revert back to their original shape, providing improved performance in controlling lost circulation and enhancing wellbore operations by maintaining hydrostatic pressure and preventing crossflows or blowouts.

Implementation Method 1

shape changing polymer structures, specifically polymeric units that can elongate or contract reversibly with temperature changes

Methodology Applied
Scientific EffectShape memory polymer: Shape Memory Polymer

Implementation Method 2

capable of reversibly extending and reversibly contracting with changes in temperature

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentUS9725635B2Methods and compositions to use shape changing polymers in subterranean formations
Publication Date: 2017.08.08 HALLIBURTON ENERGY SERVICES INC
  • US9725635B2 patent drawing
  • US9725635B2 patent drawing
  • US9725635B2 patent drawing

AI summary

A wellbore treatment fluid containing lost circulation materials and methods for using the treatment fluid, the fluid including a carrier fluid and shape changing polymer structures. The shape changing polymer structures may be folded or rolled into various cross-sectional surface area reducing configurations and are capable of reversibly extending and reversibly contracting with changes in temperature. The materials forming the shape changing polymer structures may include at least one selected from poly[ethylene-co-(vinyl acetate)], poly(ω-pentadecalactone), poly(ε-caprolactone), and copolymers thereof. A method for utilizing the treatment fluid for creation or maintenance of a well includes forming or providing the treatment fluid and introducing the treatment fluid into a borehole.