Shape Memory Polymer Bilayer Wrinkle Formation

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Solution Overview

Problem

Current methods lack efficient techniques for creating reversible and irreversible wrinkle structures without relying on traditional lithographic techniques, limiting the control and strategic formation of wrinkles in various applications.

Innovation Solution

The method involves forming a bilayer with a shape memory polymer and a rigid film layer, where the shape memory polymer is heated and cooled under controlled forces to create reversible and irreversible wrinkles, allowing for the recovery of the original shape and subsequent reformation of wrinkles at specific temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional lithographic techniques are used to create wrinkle structures, then manufacturing precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvewrinkle structure precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces traditional lithographic techniques (optical/mechanical system) with a thermal-field-based method. Shape memory polymers are heated to transition temperatures, deformed mechanically, and then cooled to create wrinkles. This substitution eliminates complex lithographic equipment while achieving comparable wrinkle precision through thermal field control and mechanical deformation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes changes in the shape memory polymer's physical parameters (temperature, phase state) to control wrinkle formation. By heating above transition temperature and cooling below it, the polymer undergoes phase changes that enable reversible deformation and wrinkle creation. This parameter-based control simplifies the process compared to lithography while maintaining precision.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If shape memory polymer is heated and cooled under controlled forces to create reversible wrinkles, then adaptability is improved, but energy consumption increases

Engineering Contradiction:
Improvewrinkle reversibilityVSAvoidthermal energy consumption
Core Design Contradiction:
Adaptability or versatilityVSUse of energy by moving object

Solution Approach 1:

The patent exploits phase transitions of the shape memory polymer (between ordered and disordered states) to achieve reversible wrinkle formation. Heating above transition temperature allows deformation, while cooling below transition temperature fixes the wrinkle structure. This phase transition mechanism enables adaptability and reversibility while using relatively low thermal energy compared to alternative methods.

Inventive Principle:
Principle #36Phase transitions

3Manufacturing precision

If multiple zones of localized deformation are created by cooling under applied force, then manufacturing precision is improved, but process time increases

Engineering Contradiction:
Improvelocalized deformation controlVSAvoidcooling and deformation time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent applies deformation force to the shape memory polymer while it is in the deformed state (above transition temperature), creating localized zones of deformation before cooling. This preliminary action allows precise control over wrinkle location and pattern. The cooling process then freezes these pre-formed zones, achieving high manufacturing precision without requiring time-consuming post-processing.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the creation of both reversible and irreversible wrinkles on the same substrate surface without traditional lithographic techniques, providing control over wrinkle formation and allowing for the manipulation of structural colors and strain history recording.

Implementation Method 1

A shape memory polymer is heated to a transition temperature and cooled while applying a first force. At least two zones of localized deformation are created by cooling the shape memory polymer while applying a first force.

Methodology Applied
Scientific EffectShape memory effect: Shape Memory Polymer

Implementation Method 2

A shape memory polymer is heated to a transition temperature and cooled while applying a first force.

Methodology Applied
Scientific EffectThermal transition: Phase Change

Implementation Method 3

A rigid film layer is secured to the shape memory polymer to form a bilayer.

Methodology Applied
Scientific EffectBilayer structure formation: Lamination

Implementation Method 4

The bilayer is heated to the transition temperature and a second force is applied to create a second set of wrinkles in the rigid film layer.

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 5

a second force is applied to create a second set of wrinkles in the rigid film layer

Methodology Applied
Scientific EffectMechanical deformation: Deformation

Data Source

PatentUS8585848B2Method of creating wrinkle structures for reversible and irreversible applications
Publication Date: 2013.11.19 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US8585848B2 patent drawing
  • US8585848B2 patent drawing
  • US8585848B2 patent drawing

AI summary

Methods of creating reversible and irreversible wrinkle structures are provided. A shape memory polymer is heated to a transition temperature and cooled while applying a first force. A rigid film layer is secured to the shape memory polymer to form a bilayer. The original shape of the shape memory polymer is recovered to create a first set of wrinkles in the rigid film layer. The bilayer is heated to the transition temperature and a second tensile force is applied to create a second set of wrinkles in the rigid film layer.