Shaped Activated Carbon Array for Low-Pressure Tank Venting

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Solution Overview

Problem

Existing tank venting systems using activated carbon packings face high pressure drops and reduced adsorptive capacity due to particle size limitations, leading to inefficient hydrocarbon vapor retention in motor fuel systems, especially under vibrations during vehicle motion.

Innovation Solution

The use of an array of shaped activated carbon articles with varying channel cross-sectional areas connected to maintain low pressure drops while enhancing adsorptive capacity, produced through a process involving carbonization and activation of carbon particles with high mesopore content, resulting in a high activated carbon content of at least 95% by weight.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If activated carbon packings are used in tank venting systems, then adsorptive capacity is achieved, but pressure drop becomes very high

Engineering Contradiction:
Improveadsorptive capacityVSAvoidpressure drop
Core Design Contradiction:
Quantity of substanceVSStress or pressure

Solution Approach 1:

The patent employs monolithic structures with controlled porosity and channel networks instead of packed particles. The monolithic activated carbon articles feature an interconnected pore system that allows vapor flow while providing adsorption sites, eliminating the high pressure drop associated with particle packings while maintaining adsorptive capacity.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent changes the physical state and structural parameters of activated carbon from particulate to monolithic form. This transformation alters the flow characteristics and pressure drop profile while preserving the adsorptive properties through controlled pore distribution and surface area within the monolithic structure.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If small particle size activated carbon is used for good regenerability, then regenerability is improved, but pressure drop increases even greater

Engineering Contradiction:
ImproveregenerabilityVSAvoidpressure drop
Core Design Contradiction:
Duration of action of stationary objectVSStress or pressure

Solution Approach 1:

The monolithic structure incorporates a controlled pore network that provides adequate surface area for adsorption and regeneration cycles without requiring small particle sizes. The interconnected pores allow vapor penetration and desorption while maintaining structural integrity and low flow resistance.

Inventive Principle:
Principle #31Porous materials

3Quantity of substance

If activated carbon particles are used in moving vehicles, then adsorption function is provided, but vibrations cause particle abrasion and pulverization reducing adsorptive capacity

Engineering Contradiction:
Improveadsorptive capacityVSAvoidmechanical stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The monolithic activated carbon structure provides a rigid, continuous framework that resists vibration-induced mechanical degradation. The monolithic form eliminates inter-particle contact and abrasion while maintaining the porous adsorption network necessary for hydrocarbon vapor capture in dynamic vehicle environments.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration achieves a significant reduction in pressure drop by up to 70% compared to conventional activated carbon packings while maintaining high adsorptive capacity, ensuring effective hydrocarbon vapor retention and mechanical stability.

Implementation Method 1

Hydrocarbons emitted by a motor fuel reservoir as a result of an increase in pressure, particularly when the motor vehicles are not in motion and are exposed, for example, to direct solar radiation in the summer months, are retained by such tank venting systems

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

produced through a process involving carbonization and activation of carbon particles with high mesopore content

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 3

carbonization and activation of carbon particles with high mesopore content, resulting in a high activated carbon content of at least 95% by weight

Methodology Applied
Scientific EffectActivation:

Data Source

PatentUS7462224B2Array of shaped activated carbon articles for tank venting systems and motor vehicles
Publication Date: 2008.12.09 HELSA AUTOMOTIVE GMBH & CO KG
  • US7462224B2 patent drawing
  • US7462224B2 patent drawing
  • US7462224B2 patent drawing

AI summary

The invention relates to an array of shaped activated carbon articles having channels extending through said array of shaped activated carbon articles, wherein said array of shaped activated carbon articles includes at least two shaped monolithic activated carbon articles containing channels, which channels of the at least two shaped monolithic activated carbon articles are connected so as to communicate with each other and the free cross-sectional areas formed by the channel cross-sections thereof have different values in said first and second shaped monolithic activated carbon articles. The invention also relates to a tank venting system and a motor vehicle containing an array of shaped activated carbon articles of the invention. Finally, the invention relates to a process for the production of said array of shaped activated carbon articles of the invention.