Shared Refrigeration System for Blue Ammonia and CO2 Liquefaction

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Solution Overview

Problem

Conventional ammonia production methods generate carbon dioxide as a byproduct, which is often released into the atmosphere. There is a need for procedures that can produce 'blue ammonia' while minimizing carbon dioxide emissions.

Innovation Solution

The proposed procedure involves a shared refrigeration system for both ammonia preparation and carbon dioxide preparation. This system includes steps such as pre-cooling, drying, condensation, and liquefaction of carbon dioxide, using ammonia as a refrigerant where possible, to achieve efficient carbon dioxide sequestration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If conventional carbon dioxide removal and sequestration processes are used, then carbon dioxide emissions are minimized, but energy consumption and system complexity increase

Engineering Contradiction:
Improvecarbon dioxide emissionsVSAvoidenergy consumption
Core Design Contradiction:
Object-generated harmful factorsVSUse of energy by stationary object

Solution Approach 1:

The patent combines the carbon dioxide removal process with the ammonia production process by integrating a shared refrigeration system. The refrigeration system serves dual purposes: it provides cooling for ammonia synthesis and simultaneously enables carbon dioxide liquefaction and sequestration. This merging of functions allows carbon dioxide to be removed and sequestered without requiring a completely separate energy-intensive system, thereby minimizing emissions while controlling energy consumption through shared infrastructure.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The refrigeration system is designed with multi-functionality, serving both the ammonia production process and the carbon dioxide sequestration process. By making the refrigeration system universal, the patent eliminates the need for separate refrigeration systems for each process, reducing overall energy consumption and system complexity while achieving effective carbon dioxide removal and minimization of emissions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If separate refrigeration systems are used for ammonia production and carbon dioxide processing, then process independence is maintained, but device complexity and investment costs increase

Engineering Contradiction:
Improveprocess independenceVSAvoidsystem complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent merges the refrigeration systems for ammonia production and carbon dioxide processing into a single shared system. This combination reduces device complexity and investment costs by eliminating redundant equipment while maintaining functional integration. The shared refrigeration system is designed to handle both processes simultaneously, achieving cost-effectiveness without sacrificing the ability to independently control each process stream through appropriate valve and heat exchanger configurations.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables significant synergy effects by utilizing a shared refrigeration system, reducing the energy requirements for carbon dioxide processing, and minimizing the need for additional refrigerants, thereby enhancing the production of blue ammonia while reducing carbon dioxide emissions.

Implementation Method 1

the carbon dioxide is typically compressed, purified if necessary, and then liquefied before being permanently stored

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

a refrigerant used in the refrigeration system of the ammonia plant to be made available for pre-cooling carbon dioxide

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 3

a shared refrigeration system for both ammonia preparation and carbon dioxide preparation

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentEP4538225A1Method and plant for producing ammonia
Publication Date: 2025.04.16 LINDE AG
  • EP4538225A1 patent drawingFigure 1
  • EP4538225A1 patent drawing
  • EP4538225A1 patent drawing

AI summary

A process (100) for the production of blue ammonia is proposed, wherein a first stream (102) is subjected to carbon dioxide removal (20) to obtain a second stream (103) and a third stream (104), the second stream (103) or a part thereof is subjected to ammonia synthesis (30) to obtain a fourth stream (105), the fourth stream (105) or a part thereof is subjected to ammonia purification (40) to obtain a fifth stream (106), and the third stream (104) or a part thereof is subjected to carbon dioxide purification (50) to obtain a sixth stream (107), wherein the first stream (102) contains hydrogen and carbon dioxide, the second stream (103) is enriched in hydrogen and depleted in carbon dioxide compared to the first stream (102).The third material stream (104) and the sixth material stream (107) are enriched in carbon dioxide and depleted in hydrogen compared to the first material stream (102), and the fourth material stream (105) and the fifth material stream (106) contain ammonia. It is proposed that the ammonia recovery (30) and the carbon dioxide recovery (50) be carried out using a shared refrigeration unit (60). A corresponding unit is also proposed.